Encapsulating nanosilica into polyacrylic acid and chitosan interpenetrating network hydrogel for preconcentration of uranium from aqueous solutions

被引:18
作者
He, Jiarui [2 ]
Jin, Jiali [2 ]
Wang, Zhenzhen [2 ]
Yin, Hongwei [2 ]
Wei, Congcong [2 ]
Xu, Xiaoping [1 ]
机构
[1] Fuzhou Univ, Coll Chem, Key Lab Pharmaceut Preparat, Fuzhou 350108, Fujian, Peoples R China
[2] Fuzhou Univ, Coll Chem, Key Lab Bipharmaceut, Fuzhou 350108, Fujian, Peoples R China
关键词
Polyacrylic acid; Uranium (VI); Chitosan; Nanosilica particles; HEAVY-METAL IONS; WASTE-WATER; REMOVAL; BIOSORPTION; ADSORPTION; COMPOSITE; CU(II); ADSORBENTS; COPPER(II); LEAD(II);
D O I
10.1007/s10967-018-6034-7
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Polyacrylic acid, Chitosan and nanosilica particles composite (PCNS) was prepared for enrichment of U (VI) from aqueous solutions. Adsorption tests controlled by different parameters including contact time, pH, initial concentration of UO2 (2+) and coexistence ions were examined. FTIR, SEM and EDX studies proved the formation of composite and confirmed efficient adsorption of UO2 (2+) by PCNS. The experimental datas fit the Langmuir and pseudo-second-order models, the R (L) (0.115-0.645) indicates the adsorption of UO2 (2+) onto PCNS are favorable. The value of q (m) (451.118 mg g(-1)) and adsorption-desorption experiments showed PCNS hydrogel can be reckoned as a high efficienct and sustainable material for removal of U (VI).
引用
收藏
页码:1299 / 1309
页数:11
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