Cycloaddition of cyclopropanes for the elaboration of medium-sized carbocycles

被引：38
作者：
Caille, Julien [1 ,2 ]
Robiette, Raphael [1 ]
机构：
[1] Catholic Univ Louvain, Inst Condensed Matter & Nanosci, Pl Louis Pasteur 1 Box L4-01-02, B-1348 Louvain La Neuve, Belgium
[2] Univ Paris Est Creteil UPEC, Inst Chim & Mat Paris Est ICMPE, UMR CNRS 7182, 2 Rue Henri Dunant, F-94320 Thiais, France
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2021年 / 19卷 / 26期
关键词：
CATALYZED 5+2 CYCLOADDITIONS; DONOR-ACCEPTOR CYCLOPROPANES; INTRAMOLECULAR 3+2+2 CYCLOADDITIONS; ASYMMETRIC TOTAL-SYNTHESIS; ETHYL CYCLOPROPYLIDENEACETATE; ENE-VINYLCYCLOPROPANES; METAL; ALKYNES; ALLENES; REACTIVITY;
D O I：
10.1039/d1ob00838b
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The stereocontrolled formation of medium-sized carbocycles is a major goal in modern organic chemistry due to their widespread occurrence in natural products and pharmaceutically active ingredients. One approach consists in the use of cycloaddition reactions which notably results in high selectivities and atom-economy. To this end, cyclopropanes are ideal substrates since they can provide readily functionalized three- or five-carbon synthons. Herein we report advances made in cycloaddition reactions of cyclopropanes towards the synthesis of medium-sized carbocycles via transition metal catalysis or Lewis acid catalysis.
引用
收藏
页码：5702 / 5724
页数：23
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