[O-Ethyl (Z)-N-(2-chlorophenyl)thiocarbamato-κS](tricyclohexylphosphine-κP)gold(I)

被引：0

作者：

Tadbuppa, Primjira P. ^{[2
]}

Tiekink, Edward R. T. ^{[1
]}

机构：

[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

[2] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2010年 / 66卷

关键词：

CRYSTAL-STRUCTURES; PH;

D O I：

10.1107/S160053681001189X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Au(C9H9ClNOS)(C18H33P)], features a slightly distorted linear coordination geometry for the Au atom defined by a S, P-donor set [S-Au-P = 177.62 (5)degrees]. The distortion is ascribed to the close approach of the O atom, which forms an intramolecular contact of 2.970 (5) angstrom. Disorder was found in the structure with two positions of equal weight being resolved for the C atoms comprising the ethoxy group.

引用

页码：M498 / U309

页数：12

共 32 条

[31] Complexes of N-thiophosphorylthiourea (EtO)2P(O)CH2C6H4-4-[NHC(S)NHP(S)(OiPr)2]with Zn(II), Cd(II), Co(II) and Cu(PPh3)(I) [J].

Safin, Damir A. ;

Babashkina, Maria G. ;

Gimadiev, Timur R. ;

Bolte, Michael ;

Pinus, Marina V. ;

Krivolapov, Dmitriy B. ;

Litvinov, Igor A. .

POLYHEDRON, 2008, 27 (13) :2978-2982

[32] New ligand substitution modes of M2(μ-SR)2(CO)8 (M = Mo, W; R = alkyl, aryl):: synthesis, structure and properties of new di-nuclear metal(I) carbonyl thiolates, [M2(μ-SPh)2(CO)xLy]n- (M = Mo, W; x=6, 8; y=0, 1; L = PhS, (Ph)2PCH2P(Ph)2 and S2CNEt2; n=1, 0) and a polymer [W2(μ-SPh)2(CO)6(Ph)2PCH2P(Ph)2]m [J].

Zhuang, BT ;

Sun, HF ;

Pan, GH ;

He, LJ ;

Wei, Q ;

Zhou, ZF ;

Peng, SQ ;

Wu, KC .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 640 (1-2) :127-139

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