[O-Ethyl (Z)-N-(2-chlorophenyl)thiocarbamato-κS](tricyclohexylphosphine-κP)gold(I)

被引:0
作者
Tadbuppa, Primjira P. [2 ]
Tiekink, Edward R. T. [1 ]
机构
[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia
[2] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
关键词
CRYSTAL-STRUCTURES; PH;
D O I
10.1107/S160053681001189X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [Au(C9H9ClNOS)(C18H33P)], features a slightly distorted linear coordination geometry for the Au atom defined by a S, P-donor set [S-Au-P = 177.62 (5)degrees]. The distortion is ascribed to the close approach of the O atom, which forms an intramolecular contact of 2.970 (5) angstrom. Disorder was found in the structure with two positions of equal weight being resolved for the C atoms comprising the ethoxy group.
引用
收藏
页码:M498 / U309
页数:12
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