Synthesis and crystal structure of [Na3(H2O)6,5(EtOH)][PhSnS3]•3EtOH

被引：0

作者：

Hanser, R ^{[1
]}

Merzweiler, K ^{[1
]}

机构：

[1] Univ Halle Wittenberg, Inst Anorgan Chem, D-06120 Halle, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1998年 / 624卷 / 01期

关键词：

tin; sulfur; crystal structure;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ph4Sn4S6 reacts with Na2S . 5H(2)O in aqueous acetone to form Na-3[PhSnS3]. Recrystallization of the crude product from ethanol leads to colourless needles of [Na-3(H2O)(6,5)(EtOH)][PhSnS3]. 3EtOH 1. The crystal structure of 1 was determined by X-ray diffraction. 1 consists of[PhSnS3](3-) anions and sodium cations which are coordinated by water, ethanol and sulfur atoms of the [PhSnS3](3-) anions. The [PhSnS3](3-) anion contains a tin atom which is coordinated nearly tetrahedrally by a phenyl group and three sulfur atoms. The Sn-S bonds are 237,4(2)-238,4(2) pm.

引用

页码：10 / 12

页数：3

共 7 条

[1] THIASTANNACYCLOHEXANES (R2SNS)3 AND ADAMANTANES (RSN)4S6 - SYNTHESES, PROPERTIES, AND STRUCTURES [J].

BERWE, H ;

HAAS, A .

CHEMISCHE BERICHTE-RECUEIL, 1987, 120 (07) :1175-1182

[2]

DIAMOND, 1996, VISUELLES INFORMATIO

[3]

Krebs B., 1970, ANGEW CHEM, V82, P884

[4] PREPARATION AND STRUCTURE OF K2SNS3 2 H2O [J].

SCHIWY, W ;

BLUTAU, C ;

GATHJE, D ;

KREBS, B .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1975, 412 (01) :1-10

[5] PREPARATION AND CRYSTAL-STRUCTURE OF NA4SNS4.14H2O . 14H2O [J].

SCHIWY, W ;

POHL, S ;

KREBS, B .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1973, 402 (01) :77-86

[6]

SHELDRICK GM, 1986, SHELXS86 SHELXL93 PR

[7]

SHELDRICK GM, 1993, SHELXS86 SHELXL93 PR

← 1 →