Tip-to-tip assembly of urchin-like Au nanostar at water-oil interface for surface-enhanced Raman spectroscopy detection

被引:17
作者
Cong, Tianze [1 ]
Wang, Jianzhen [1 ]
Zhao, Yongpeng [1 ,2 ]
Zhang, Dongmei [1 ]
Fan, Zeng [1 ]
Pan, Lujun [1 ]
机构
[1] Dalian Univ Technol, Sch Phys, 2 Linggong Rd, Dalian 116024, Peoples R China
[2] Dalian Univ Technol, Sch Microelect, 2 Linggong Rd, Dalian 116024, Liaoing, Peoples R China
基金
中国国家自然科学基金;
关键词
Surface-enhanced Raman spectroscopy; Au nanostar; Water-oil interface; Nanogap; Finite-difference time-domain; ULTRASENSITIVE DETECTION; SERS SUBSTRATE; NANOPARTICLES; PERFORMANCE; SCATTERING; MONOLAYER; EFFICIENT; STRATEGY; NANOFILM; MERCURY;
D O I
10.1016/j.aca.2021.338323
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Au Nanostar (NS) monolayer as a surface enhanced Raman scattering (SERS) substrate has been synthesized by self-assembly at a water-oil interface. It is confirmed from the experiment and simulation results that the Au NS monolayer includes lots of "hot spots" at or between the tips of the Au NSs, enhancing the local electromagnetic fields and giving rise to strong SERS signals sequentially. The limit of detection is determined to be down to 4.2 x 10(-12) M for rhodamine 6G. Furthermore, the Au NS monolayer can detect multiple molecules, including thiabendazole, methylene blue, 4-mercaptobenzoic acid, and p-amino thiophenol, indicating that the SERS substrate composed of Au NS monolayer has potential applications in analytical chemistry, food safety, and environmental safety. (C) 2021 Elsevier B.V. All rights reserved.
引用
收藏
页数:9
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