Synthesis and crystal structure of a new mononuclear copper complex

被引：0
|
作者：
Fan, C [1 ]
Chen, CN [1 ]
Ma, CB [1 ]
Chen, F [1 ]
Liu, QT [1 ]
机构：
[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2002年 / 21卷 / 06期
关键词：
synthesis; crystal structure; tpmb; Cu complex;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new kind of Cu (II) complex [Cu(tpmb)(2)Cl-2].CH3OH.H2O (tpmb = 1,3,5-tri(2-pyrimidinyl)sulfanyhnethyl-2,4,6-trimelhylbenzene) was synthesized, and its structure has been determined by X-ray single-crystal diffraction. It crystallizes in the triclinic, space group P (1) over bar with a = 8.8397(2), b = 13.327(3), c = 13.926(3) Angstrom, alpha = 63.27(3), beta = 86.96(3), gamma = 80.68(3)degrees, V = 1445.6(5) Angstrom(3), C49H51Cl2CuN12O2S6, M-r = 1166.82, Z = 1, F(000) = 604, D-c = 1.340 g/cm(3), mu = 0.735 mm(-1), R = 0.0545 and wR = 0.1575 for 4521 observed reflections (I > 2sigma(I)). X-ray analysis reveals that the Cu (II) ion is coordinated by two Cl- anions and two nitrogen atoms from different pyrimidine groups, forming a square structure.
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收藏
页码：643 / 645
页数：3
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