Isostructural iron(iii) spin crossover complexes with a tridentate Schiff base-like ligand: X-ray structures and magnetic properties

被引：16

作者：

Dankhoff, Katja ^{[1
]}

Weber, Birgit ^{[1
]}

机构：

[1] Univ Bayreuth, Dept Chem, Univ Str 30, D-95447 Bayreuth, Germany

来源：

DALTON TRANSACTIONS | 2019年 / 48卷 / 41期

关键词：

Single crystals - Iron compounds - Inorganic compounds;

D O I：

10.1039/c9dt00846b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Here we present two isostructural iron(iii) spin crossover complexes with the same tridentate ligand and perchlorate or tetrafluoroborate as counter ion. Single crystal X-ray structures in the high spin and low spin state were obtained for both complexes. An abrupt spin transition above 100 K is observed with the transition temperature depending on the size of the anion.

引用

页码：15376 / 15380

页数：5

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