Composite hydroxyapatite-PTFE coatings on Mg-Mn-Ce alloy for resorbable implant applications via a plasma electrolytic oxidation-based route

被引:51
作者
Gnedenkov, S. V. [1 ]
Sinebryukhov, S. L. [1 ]
Zavidnaya, A. G. [1 ]
Egorkin, V. S. [1 ]
Puz, A. V. [1 ]
Mashtalyar, D. V. [1 ]
Sergienko, V. I. [1 ]
Yerokhin, A. L. [2 ]
Matthews, A. [2 ]
机构
[1] Russian Acad Sci, Inst Chem, Far East Branch, Vladivostok 690022, Russia
[2] Univ Sheffield, Dept Mat Sci & Engn, Sheffield, S Yorkshire, England
基金
英国工程与自然科学研究理事会;
关键词
Mg-Mn-Ce alloy; Biodegradable implants; Plasma electrolytic oxidation; Hydroxyapatite; Corrosion; Composite coatings; CALCIUM-PHOSPHATE; MAGNESIUM;
D O I
10.1016/j.jtice.2014.03.022
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Multifunctional corrosion resistant and bioactive coatings containing hydroxyapatite Ca-10(PO4)(6)(OH)(2) and magnesium oxide MgO were obtained on Mg-Mn-Ce alloy by plasma electrolytic oxidation. The phase and elemental composition, morphology and anticorrosion properties of the coatings were investigated. The PEO layers were post-treated using Forum (R) superdispersed polytetrafluoroethylene powder, which caused a considerable reduction of the magnesium alloy corrosion rate (>4 orders of magnitude). In particular, the polarisation resistance has increased, as a result of such duplex treatment, by five orders of magnitude. The composite coatings are considered promising to induce bioactivity and control corrosion degradation of resorbable Mg implants. (C) 2014 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:3104 / 3109
页数:6
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