Inhibiting Effect of Ciprofloxacin, Norfloxacin and Ofloxacin on Corrosion of Mild Steel in Hydrochloric Acid

被引:42
作者
Pang Xuehui [1 ,2 ]
Ran Xiangbin [3 ]
Kuang Fei [4 ]
Xie Jiandong [5 ]
Hou Baorong [2 ]
机构
[1] Univ Jinan, Sch Chem & Chem Engn, Jinan 250022, Peoples R China
[2] Chinese Acad Sci, Inst Oceanol, Qingdao 266071, Peoples R China
[3] SOA, Res Ctr Marine Ecol, Inst Oceanog 1, Qingdao 266061, Peoples R China
[4] SW Petr Univ, Sch Chem & Chem Engn, Chengdu 637001, Peoples R China
[5] Shandong Jianzhu Univ, Jinan 250014, Peoples R China
基金
中国博士后科学基金;
关键词
corrosion; inhibition; electrochemical impedance spectroscopy; potentiodynamic polarization; X-ray photoelectron spectroscopy; CARBON-STEEL; ADSORPTION; EFFICIENCY; DERIVATIVES; PROTECTION; BEHAVIOR; MEDIA;
D O I
10.1016/S1004-9541(08)60362-6
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The inhibiting effect of ciprofloxacin, norfloxacin and ofloxacin on the corrosion of mild steel in 1 mol.L-1 HCl and the mechanism were studied at different temperatures using mass loss measurement, electrochemical method, and X-ray photoelectron spectroscopy (XPS). Effective inhibition was shown by mass loss, potentiodynamic polarization and impedance spectroscopy measurement. The corrosion rate of the metal in the mass loss measurement, and the corrosion reaction on cathode and anode in the electrochemical measurement were accelerated when temperature was increased. XPS results showed that the inhibitors adsorbed effectively on the metal surface.
引用
收藏
页码:337 / 345
页数:9
相关论文
共 40 条
[1]   CeCl3 and LaCl3 binary solutions as environment-friendly corrosion inhibitors of AA5083 Al-Mg alloy in NaCl solutions [J].
Aballe, A ;
Bethencourt, M ;
Botana, FJ ;
Marcos, M .
JOURNAL OF ALLOYS AND COMPOUNDS, 2001, 323 :855-858
[2]   The corrosion inhibition of mild steel by 3-formyl-8-hydroxy quinoline in hydrochloric acid medium [J].
Achary, Ganesha ;
Sachin, H. R. ;
Naik, Y. Arthoba ;
Venkatesha, T. V. .
MATERIALS CHEMISTRY AND PHYSICS, 2008, 107 (01) :44-50
[3]   Inhibition of 5083 aluminium alloy and galvanised steel by lanthanide salts [J].
Arenas, MA ;
Bethencourt, M ;
Botana, FJ ;
de Damborenea, J ;
Marcos, M .
CORROSION SCIENCE, 2001, 43 (01) :157-170
[4]   Corrosion inhibition of indole-3-acetic acid on mild steel in 0.5 M HCl [J].
Avci, Guelsen .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2008, 317 (1-3) :730-736
[5]   2,5-bis(n-methoxyphenyl)-1,3,4-oxadiazoles used as corrosion inhibitors in acidic media:: correlation between inhibition efficiency and chemical structure [J].
Bentiss, F ;
Traisnel, M ;
Chaibi, N ;
Mernari, B ;
Vezin, H ;
Lagrenée, M .
CORROSION SCIENCE, 2002, 44 (10) :2271-2289
[6]   Inhibition of acidic corrosion of mild steel by 3,5-diphenyl-4H-1,2,4-triazole [J].
Bentiss, F ;
Traisnel, M ;
Gengembre, L ;
Lagrenée, M .
APPLIED SURFACE SCIENCE, 2000, 161 (1-2) :194-202
[7]   Formation and behaviour study of an environment-friendly corrosion inhibitor by electrochemical methods [J].
Bommersbach, P ;
Alemany-Dumont, C ;
Millet, JP ;
Normand, B .
ELECTROCHIMICA ACTA, 2005, 51 (06) :1076-1084
[8]   Synthesis of bolaamphiphile surfactants and their inhibitive effect on carbon steel corrosion in hydrochloric acid medium [J].
Chebabe, D ;
Chikh, ZA ;
Dermaj, A ;
Rhattas, K ;
Jazouli, T ;
Hajjaji, N ;
El Mdari, F ;
Srhiri, A .
CORROSION SCIENCE, 2004, 46 (11) :2701-2713
[9]   Experimental and theoretical study of 1-(2-ethylamino)-2-methylimidazoline as an inhibitor of carbon steel corrosion in acid media [J].
Cruz, J ;
Martínez, R ;
Genesca, J ;
García-Ochoa, E .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2004, 566 (01) :111-121
[10]   Some chitin/chitosan derivatives for corrosion protection and waste water treatments [J].
El-Sawy, SM ;
Abu-Ayana, YM ;
Abdel-Mohdy, FA .
ANTI-CORROSION METHODS AND MATERIALS, 2001, 48 (04) :227-234