Terahertz absorption spectra of 8-hydroxyquinoline and its some metal complexes

被引：6
作者：
Liu, Guifeng [1 ,2 ]
Ma, Shihua [1 ]
Zhao, Hongwei [1 ]
Ji, Te [1 ]
Zhang, Zengyan [1 ]
Wang, Wenfeng [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Appl Phys, Shanghai 201800, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2009年 / 936卷 / 1-3期
基金：
中国国家自然科学基金;
关键词：
Terahertz; THz-TDS; 8-Hydroxyquinoline; DFT; Metal complexes; ANHYDROUS COPPER 8-HYDROXYQUINOLINATE; TIME-DOMAIN SPECTROSCOPY; VIBRATIONAL-SPECTRA; MOLECULAR-STRUCTURE; OPTICAL-PROPERTIES; THIN-FILMS; CRYSTAL; TRIS(8-HYDROXYQUINOLINE)ALUMINUM(III); TECHNOLOGY; STATE;
D O I：
10.1016/j.molstruc.2009.07.015
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The room temperature terahertz (THz) absorption spectra of 8-hydroxyquinoline (8HQ) and tris(8-hydroxyquinolino)aluminum, bis-(8-hydroxyquinolinato)zinc and copper 8-hydroxyquinoline were clearly measured from 0.3 to 1.8 THz. 8HQ has absorption peaks which occur at 1.02, 1.48, and 1.77 THz. Density functional theory (DFT) was used to predict the vibration frequencies of 8HQ in the frequency range 0-10 THz. Metal complexes have various absorption peaks in the THz region, which may be related to different metal ions and used to distinguish them. These results show that THz-TDS are sensitive tools for characterization of metal complexes. Crown Copyright (C) 2009 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码：56 / 59
页数：4
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