Gold nanoparticles decorated MnO2 nanowires for high performance supercapacitor

被引:51
作者
Khandare, Lina [1 ]
Terdale, Santosh [1 ]
机构
[1] Savitribai Phule Pune Univ, Dept Chem, Pune 411007, Maharashtra, India
关键词
MnO2; nanowire; Gold nanoparticles decorated MnO2; Supercapacitor; ELECTROCHEMICAL PERFORMANCE; FLEXIBLE SUPERCAPACITORS; NANOSTRUCTURED MATERIALS; OXIDE; PHOTOLUMINESCENCE; NANOSHEETS; ELECTRODE; POLYANILINE; TEMPERATURE; FRAMEWORK;
D O I
10.1016/j.apsusc.2016.12.036
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We have synthesized highly crystalline MnO2 nanowires by wet chemical biphasic method. Further, the gold nanoparticles were decorated on MnO2 nanowires. The MnO2 nanowire and gold nanopartide decorated MnO2 nanowire samples were well characterized using X-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM), transmission electron microscopy (TEM), photoluminescence (PL) spectroscopy etc. The supercapacitor performance for both the samples was tested under the identical conditions. The gold nanoparticles decorated on MnO2 nanowire exhibits cyclic stability cycles with only 3% capacity loss and maximum energy density of 37.08 Wh/kg. It has been observed that the gold decorated MnO2 nanowire shows superior performance towards supercapacitor application due to the increased defects, surface area and increase in the capacity towards charge storage. Our results can open up new avenue towards utilization of MnO2 nanowires and other metal oxide nanomaterials with controlled functionalization/decoration of metal nanoparticles for superior charge storage devices. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:22 / 29
页数:8
相关论文
共 51 条
[1]  
Acerce M, 2015, NAT NANOTECHNOL, V10, P313, DOI [10.1038/NNANO.2015.40, 10.1038/nnano.2015.40]
[2]   Optical absorption and photoluminescence studies of gold nanoparticles deposited on porous silicon [J].
Amran, Tengku Sarah Tengku ;
Hashim, Md Roslan ;
Al-Obaidi, Nihad K. Ali ;
Yazid, Hanani ;
Adnan, Rohana .
NANOSCALE RESEARCH LETTERS, 2013, 8 :1-6
[3]   Synthesis of layered LiMnO2 as an electrode for rechargeable lithium batteries [J].
Armstrong, AR ;
Bruce, PG .
NATURE, 1996, 381 (6582) :499-500
[4]   Photoluminescence quenching in gold - MoS2 hybrid nanoflakes [J].
Bhanu, Udai ;
Islam, Muhammad R. ;
Tetard, Laurene ;
Khondaker, Saiful I. .
SCIENTIFIC REPORTS, 2014, 4
[5]   Self-doped polyaniline on functionalized carbon cloth as electroactive materials for supercapacitor [J].
Bian, Li-Jun ;
Luan, Feng ;
Liu, Sha-Sha ;
Liu, Xiao-Xia .
ELECTROCHIMICA ACTA, 2012, 64 :17-22
[6]   Electrospun α-Fe2O3 nanostructures for supercapacitor applications [J].
Binitha, G. ;
Soumya, M. S. ;
Madhavan, Asha Anish ;
Praveen, P. ;
Balakrishnan, A. ;
Subramanian, K. R. V. ;
Reddy, M. V. ;
Nair, Shantikumar V. ;
Nair, A. Sreekumaran ;
Sivakumar, N. .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (38) :11698-11704
[7]   Vibrational spectroscopy of bulk and supported manganese oxides [J].
Buciuman, F ;
Patcas, F ;
Craciun, R ;
Zahn, DRT .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1999, 1 (01) :185-190
[8]   Exfoliation of Bulk Inorganic Layered Materials into Nanosheets by the Rapid Quenching Method and Their Electrochemical Performance [J].
Chakravarty, Disha ;
Late, Dattatray J. .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2015, (11) :1973-1980
[9]   Microwave-Assisted Synthesis of Few-Layered TaTe2 and Its Application as Supercapacitor [J].
Chakravarty, Disha ;
Kumar, Praveen ;
Ugale, Vaishali S. ;
Late, Dattatray J. .
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2015, (09) :1598-1603
[10]   Three-dimensional scaffolding framework of porous carbon nanosheets derived from plant wastes for high-performance supercapacitors [J].
Chen, Chong ;
Yu, Dengfeng ;
Zhao, Gongyuan ;
Du, Baosheng ;
Tang, Wei ;
Sun, Lei ;
Sun, Ye ;
Besenbacher, Flemming ;
Yu, Miao .
NANO ENERGY, 2016, 27 :377-389