Hydrogen incorporation in diamond: The nitrogen-vacancy-hydrogen complex

被引：90
作者：
Glover, C [1 ]
Newton, ME
Martineau, P
Twitchen, DJ
Baker, JM
机构：
[1] Univ Warwick, Dept Phys, Coventry CV4 7AL, W Midlands, England
[2] DTC Res Ctr, Maidenhead SL6 6JW, Berks, England
[3] Element Six Ltd, Ascot SL5 8BP, Berks, England
[4] Univ Oxford, Clarendon Lab, Oxford OX1 3PU, England
来源：
PHYSICAL REVIEW LETTERS | 2003年 / 90卷 / 18期
关键词：
D O I：
10.1103/PhysRevLett.90.185507
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
We report the identification of the nitrogen-vacancy-hydrogen complex in a freestanding nitrogen-doped isotopically engineered single crystal diamond synthesized by chemical vapor deposition. The hydrogen atom is located in the vacancy of a nearest-neighbor nitrogen-vacancy defect and appears to be bonded to the nitrogen atom maintaining the trigonal symmetry of the center. The defect is observed by electron paramagnetic resonance in the negative charge state in samples containing a suitable electron donor (e.g., substitutional nitrogen N-S(0)).
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页数：4
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