Synthesis and characterization of [(Me3SiCH2)2GaP(SiMe3)2]2, an example of a gallium-phosphorus dimer obtainable only through an indirect reaction pathway

被引：0
作者：
Wells, RL [1 ]
Foos, EE
Baldwin, RA
Rheingold, AL
Yap, GPA
机构：
[1] Duke Univ, Dept Chem, Durham, NC 27708 USA
[2] Univ Delaware, Dept Chem, Newark, DE 19716 USA
来源：
HETEROATOM CHEMISTRY | 1998年 / 9卷 / 02期
关键词：
D O I：
10.1002/(SICI)1098-1071(1998)9:2<147::AID-HC8>3.3.CO;2-G
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The dimeric gallium-phosphorus compound [(Me3SiCH2)(2)GaP(SiMe3)(2)](2) (1) was prepared from the 1:1 mole ratio lithium-halide elimination reaction of (Me3SiCH2)(2)GaP(SiMe3)(2)Ga(CH2SiMe3)(2)Cl with LiP(SiMe3)(2) in benzene solution and has been characterized through multinuclear solution NMR, partial elemental analysis, and single-crystal X-ray analysis. Compound 1 could not be obtained from the direct reactions of (Me3SiCH2)(2)GaCl with P(SiMe3)(3) or LiP(SiMe3)(2). (C) 1998 John Wiley & Sons, Inc.
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页码：147 / 150
页数：4
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