Optical transitions and up-conversion emission of Tm3+-singly doped and Tm3+/Yb3+-codoped oxyfluoride glasses

被引：12

作者：

Feng, Li

Tang, Qiang

Liang, Lifang

Wang, Jing

Liang, Hongbin

Su, Qiang ^{[1
]}

机构：

[1] Sun Yat Sen Zhongshan Univ, State Key Lab Optoelect Mat & Technol, Sch Chem & Chem Engn, Guangzhou 510275, Peoples R China

[2] Sun Yat Sen Zhongshan Univ, Dept Phys, Guangzhou 510275, Peoples R China

[3] Guangxi Normal Coll, Dept Chem, Nanning 530001, Peoples R China

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2007年 / 436卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

optical properties; up-conversion; Judd-Ofelt theory; glasses;

D O I：

10.1016/j.jallcom.2006.07.022

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Novel oxyfluoride glasses SiO2-Al2O3-Na2O-ZnF2 doped with Tm3+ and Tm3+/Yb3+ were fabricated. The optical properties of the synthesized glasses were experimentally and theoretically investigated in detail. According to the Judd-Ofelt theory, the Judd-Ofelt intensity parameters were calculated. With these intensity parameters, the radiative transition probabilities, fluorescence branching ratios and radiative lifetimes were obtained. The fluorescence lifetime and quantum efficiency for D-1(2)->->, F-3(4) emission of TM3+ -singly doped glass were determined to be 12 mu s, and 35.3%, respectively. The up-conversion luminescence was observed upon excitation with 980 nm diode laser. The dependence of the up-conversion emission intensity upon the excitation power was examined, and the up-conversion mechanisms were discussed. (C) 2006 Elsevier B.V. All rights reserved.

引用

页码：272 / 277

页数：6

共 33 条

[21] Optical spectroscopy and frequency upconversion properties of Tm3+ doped tungstate fluorophosphate glasses [J].

Poirier, G ;

Jerez, VA ;

de Araújo, CB ;

Messaddeq, Y ;

Ribeiro, SJL ;

Poulain, M .

JOURNAL OF APPLIED PHYSICS, 2003, 93 (03) :1493-1497

[22]

Prakash GV, 2000, MATER LETT, V46, P15, DOI 10.1016/S0167-577X(00)00135-X

[23] Efficient blue up-conversion luminescence of Tm3+ ions in transparent oxyfluoride glass ceramics containing PbxCd1-xF2 nanocrystals [J].

Qiu, J ;

Mukai, A ;

Makishima, A ;

Kawamoto, Y .

JOURNAL OF PHYSICS-CONDENSED MATTER, 2002, 14 (50) :13827-13834

[24] DEPENDENCE OF SPONTANEOUS EMISSION AND NONRADIATIVE RELAXATIONS OF TM3+ AND ER3+ ON GLASS HOST AND TEMPERATURE [J].

REISFELD, R ;

ECKSTEIN, Y .

JOURNAL OF CHEMICAL PHYSICS, 1975, 63 (09) :4001-4012

[25] LASER-DIODE-PUMPED 106 MW BLUE UP-CONVERSION FIBER LASER [J].

SANDERS, S ;

WAARTS, RG ;

MEHUYS, DG ;

WELCH, DF .

APPLIED PHYSICS LETTERS, 1995, 67 (13) :1815-1817

[26]

Su Q., 1993, CHEM RARE EARTHS

[27]

Su Q, 1986, RARE EARTHS SPECTROS, P386

[28] COMPOSITIONAL DEPENDENCE OF JUDD-OFELT PARAMETERS OF ER3+ IONS IN ALKALI-METAL BORATE GLASSES [J].

TANABE, S ;

OHYAGI, T ;

SOGA, N ;

HANADA, T .

PHYSICAL REVIEW B, 1992, 46 (06) :3305-3310

[29] Evidence of the influence of phonon density on Tm3+ upconversion luminescence in tellurite and germanate glasses [J].

Tsang, WS ;

Yu, WM ;

Mak, CL ;

Tsui, WL ;

Wong, KH ;

Hui, HK .

JOURNAL OF APPLIED PHYSICS, 2002, 91 (04) :1871-1874

[30] OPTICAL INTENSITIES OF RARE-EARTH IONS IN YTTRIUM ORTHOALUMINATE [J].

WEBER, MJ ;

VARITIMOS, TE ;

MATSINGER, BH .

PHYSICAL REVIEW B, 1973, 8 (01) :47-53

← 1 2 3 4 →