Preparation of titanium dioxide nanostructure from ilmenite through sulfate-leaching process and solvent extraction by D2EHPA

被引:14
作者
Anbia, Mansoor [1 ]
Ahmadian, Fatimah [1 ]
Rezaie, Marzie [1 ]
机构
[1] Iran Univ Sci & Technol, Res Lab Nanoporous Mat, Fac Chem, Farjam St, Tehran 1684613114, Iran
基金
美国国家科学基金会;
关键词
Ilmenite leaching; Solvent extraction; Anatase; TiO2; nanoparticles; Bis-(2-ethyl-hexyl) phosphoric acid (D(2)EHPA); PANZHIHUA ILMENITE; SULFURIC-ACID; TIO2; DEGRADATION; NANOPARTICLES; ADSORBENTS; PARTICLES; ANATASE; RUTILE; LIGHT;
D O I
10.1007/s13738-018-1441-9
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this study, TiO2 nanoparticles have been obtained from low-grade ilmenite ore via two consecutive acid digestion and solvent extraction processes. The as-extracted TiO2 (Anatase phase) product was characterized using techniques such as XRD, XRF, FESEM, FTIR and BET surface area. Diluted sulfuric acid and D(2)EHPA (bis-(2-ethyl-hexyl) phosphoric acid) were used as digester agent and an extraction solvent, respectively. The effects of main parameters such as recycling capacities and D(2)EHPA concentration, as well as the extraction time and temperature on TiO2 extraction were investigated. The results demonstrated that the best performance and efficiency for titanium and total iron uptake were 99 and 3.8%, respectively, at the lowest concentration of D(2)EHPA.
引用
收藏
页码:2533 / 2540
页数:8
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