Zwitterionic Ladder Bis(arylethenyl)benzenes with Large Two-Photon Absorption Cross Sections

被引：39
作者：
Fukazawa, Aiko [1 ]
Yamada, Hiroshi [1 ]
Sasaki, Yutaka [2 ]
Akiyama, Seiji [2 ]
Yamaguchi, Shigehiro [1 ]
机构：
[1] Nagoya Univ, Dept Chem, Grad Sch Sci, Chikusa Ku, Nagoya, Aichi 4648602, Japan
[2] Sci & Technol Res Ctr Inc, Mitsubishi Chem Grp, Aoba Ku, Yokohama, Kanagawa 2778502, Japan
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2010年 / 5卷 / 03期
基金：
日本学术振兴会;
关键词：
boron; phosphorus; pi interactions; two-photon absorption; zwitterions; NONLINEAR-OPTICAL-PROPERTIES; A-PI-A; MOLECULAR-STRUCTURES; TRIVALENT BORON; SINGLE-PHOTON; ORGANOBORON COMPOUNDS; CRYSTAL-STRUCTURES; ORGANIC-MOLECULES; ACCEPTOR; DONOR;
D O I：
10.1002/asia.200900517
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Various phosphonium- and borate-bridged bis(arylethenyl)benzenes were synthesized. The large two-photon absorption (TPA) cross sections in these zwitterionic ladder π-electron systems revealed that the introduction of zwitterionic bridges in the coplanar π-conjugated framework is a powerful strategy for designing excellent TPA materials. 2010 Wiley-VCH Verlag GmbH&Co. KGaA.
引用
收藏
页码：466 / 469
页数：4
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