Synthesis, structural characterisation and electronic behaviour of iron(II) and nickel(II) complexes of N,N-bis(2-pyridylmethyl)aniline

被引：44
作者：
Hazell, A
McKenzie, CJ
Nielsen, LP
机构：
[1] Univ So Denmark, Dept Chem, DK-5230 Odense M, Denmark
[2] Aarhus Univ, Inst Chem, DK-8000 Aarhus, Denmark
来源：
POLYHEDRON | 2000年 / 19卷 / 11期
关键词：
nickel(II); iron(II); crystal structures; electronic spectra;
D O I：
10.1016/S0277-5387(00)00409-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Ni(II) and Fe(II) complexes of the new ligand N,N-bis(2-pyridylmethyl)aniline (phdpa) of the general formula [M(phdpa)(2)](ClO4)(2) have been prepared and characterised. [Ni(phdpa)(2)](ClO4)(2). 0.5H(2)O was characterised by X-ray crystallography. For comparison, the X-ray structure of [Ni(medpa)(2)](ClO4)(2) (where medpa is bis(2-pyridylmethyl)methylamine) has been determined. The ligand in both [Ni(phdpa)(2)](ClO4)(2) and [Ni(medpa)2](ClO4)(2) exhibit cis-facial geometry. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1333 / 1338
页数：6
相关论文
共 17 条
  • [1] [Anonymous], 1974, INT TABLES XRAY CRYS, VIV
  • [2] BINUCLEAR CHROMIUM(III) COMPLEXES WITH SQUARATE AND BIS(2-PYRIDYLMETHYL)AMINE - CRYSTAL-STRUCTURE AND MAGNETIC CHARACTERIZATION OF DI-MU-HYDROXOBIS[(BIS(2-PYRIDYLMETHYL)-AMINE)SQUARATOCHROMIUM(III)] HYDRATE
    BANG, E
    MICHELSEN, K
    NIELSEN, KM
    PEDERSEN, E
    [J]. ACTA CHEMICA SCANDINAVICA, 1989, 43 (08): : 748 - 753
  • [3] Copper complexes of a p-phenylenediamine-based bis(tridentate) ligand
    Buchen, T
    Hazell, A
    Jessen, L
    McKenzie, CJ
    Nielsen, LP
    Pedersen, JZ
    Schollmeyer, D
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (15): : 2697 - 2703
  • [4] BUCHEN T, COMMUNICATION
  • [5] Burnett M.N., 1996, ORTEP-III: Oak Ridge Thermal Ellipsoid Plot Program for Crystal Structure Illustrations
  • [6] STRUCTURAL ASPECTS OF THE BIS(2,2'-DIPICOLYLAMINE)IRON(II) CATION
    BUTCHER, RJ
    ADDISON, AW
    [J]. INORGANICA CHIMICA ACTA, 1989, 158 (02) : 211 - 215
  • [7] SIRWARE
    Cascarano, G.
    Altomare, A.
    Giacovazzo, C.
    Guagliardi, A.
    Moliterni, A. G. G.
    Siliqi, D.
    Burla, M. C.
    Polidori, G.
    Camalli, M.
    [J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 1996, 52 : C79 - C79
  • [8] Iron(II) polyamine chemistry: Variation of spin state and coordination number in solid state and solution with iron(II) tris(2-pyridylmethyl)amine complexes
    Diebold, A
    Hagen, KS
    [J]. INORGANIC CHEMISTRY, 1998, 37 (02) : 215 - 223
  • [9] SYNTHESIS AND CHARACTERIZATION OF BIS(2-PYRIDYLMETHYL)AMINE COMPLEXES OF MANGANESE(II), ZINC(II), AND CADMIUM(II)
    GLERUP, J
    GOODSON, PA
    HODGSON, DJ
    MICHELSEN, K
    NIELSEN, KM
    WIEHE, H
    [J]. INORGANIC CHEMISTRY, 1992, 31 (22) : 4611 - 4616
  • [10] Mono-, di- and poly-nuclear transition-metal complexes of a bis(tridentate) ligand: towards p-phenylenediamine-bridged co-ordination polymers
    Hazell, A
    McKenzie, CJ
    Nielsen, LP
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (11): : 1751 - 1756
12