Polycyclic aromatic hydrocarbons contamination in surface soil of China: A review

This paper reviews the concentration, distribution, source, and potential risk of polycyclic aromatic hydrocarbons (PAHs) in surface soils of China through analysis of data from >6000 surface soil samples in nearly 100 references. The mean value of total 16 PAHs was 730 ng.g(-1) in surface soil in China, a relatively lower or moderate level than other countries. Based on the Maliszewska-Kordybach classification criteria, the proportions of heavily contaminated, contaminated, weakly contaminated, and non-contaminated soil samples were 21.4%, 11.9%, 49.5%, and 17.2%, respectively. There was a clear geographical distribution, with concentrations of the total 16 PAHs descending in the following order: Northeast China (1467 ng.g(-1)) > North China (911 ng.g(-1)) > East China (737 ng.g(-1)) > South China (349 ng.g(-1)) > West China (209 ng.g(-1)). Moreover, it was found that the PAH concentrations in surface soil in China descended along the urban-suburban-rural gradient. The concentration and distribution of PAHs were mainly related to the degree of economic development, population density, climatic conditions, and soil organic matter, and the divergence of regional economic patterns and climatic conditions was the main reason for the observed PAH distribution in the soils. Traffic emissions, coal and biomass combustion mainly contributed to the PAH contamination of surface soil in China during the process of urbanization and industrialization, and the average Benzo(a) pyrene equivalent concentration ofSPAH7c (seven carcinogenic PAHs) was 99 ng.g(-1), which indicated the soil samples had a small potential carcinogenic risk. Despite soil pollution being generally low, PAH concentrations in some areas were relatively high, therefore it is necessary to produce strategies, such as establishing effective guidelines and developing environmental-friendly technology to reduce PAH emissions, and prevent further contamination. (C) 2017 Elsevier B.V. All rights reserved.