Photoswitchable metal organic frameworks: turn on the lights and close the windows

被引：108
作者：
Castellanos, S. [1 ]
Kapteijn, F. [1 ]
Gascon, J. [1 ]
机构：
[1] Delft Univ Technol, Dept Chem Engn, Catalysis Engn, Julianalaan 136, NL-2628 BL Delft, Netherlands
来源：
CRYSTENGCOMM | 2016年 / 18卷 / 22期
基金：
欧洲研究理事会;
关键词：
POST-SYNTHETIC MODIFICATION; PHOTOCHROMIC DIARYLETHENE; ORTHO-FLUOROAZOBENZENES; AZOBENZENE; MOLECULES; CRYSTALS; FILMS; ADSORPTION; CONVERSION; SWITCHES;
D O I：
10.1039/c5ce02543e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The ability of modulating the properties of metal-organic frameworks (MOF) on demand by external light-stimuli is a most appealing pathway to enhance their performance in storage and separation and to render novel advanced applications. Photoswitchable linkers of different nature have been inserted in several MOF structures either as integral parts of their scaffolds or as guests in the pores. In this highlight we analyse the different strategies and expose some aspects that should be considered in the design of new generations of photoswitchable MOFs.
引用
收藏
页码：4006 / 4012
页数：7
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