Bis[bis(N,N-diethyldithiocarbamato)zinc(II)](trans-1,2-bis(4-pyridyl)ethylene)trans-1,2-bis(4-pyridyl)ethylene lattice adduct

被引：23

作者：

Lai, CS ^{[1
]}

Tiekink, ERT ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2003年 / 17卷 / 04期

关键词：

crystal structure; zinc; dithiocarbamate; diimine adduct; lattice adduct;

D O I：

10.1002/aoc.420

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The dimeric and centrosymmetric structure of [Zn(S2CNEt2)2(trans-NC5H4C(H)=C(H)C5H4N)](2) shows bidentate coordination by the dithiocarbamate ligands and a distorted square pyramidal geometry for zinc, defined by a NS4 donor set with the N atom in the apical position. The compound co-crystallises with a centrosymmetric molecule of trans-NC5H4C(H)=C(H)C5H4N that does not form a significant interaction to the Zn atom. Copyright (C) 2003 John Wiley Sons, Ltd.

引用

页码：251 / 252

页数：2

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