Asymmetric Si-O coupling of alcohols

被引：90
|
作者：
Weickgenannt, Andreas [1 ]
Mewald, Marius [1 ]
Oestreich, Martin [1 ]
机构：
[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2010年 / 8卷 / 07期
关键词：
SILICON-STEREOGENIC SILANES; NONENZYMATIC KINETIC RESOLUTION; DONOR-FUNCTIONALIZED ALCOHOLS; ORGANOSILICON COMPOUNDS; RHODIUM COMPLEXES; STEREOSELECTIVE SILYLATION; SECONDARY ALCOHOLS; CHIRALITY TRANSFER; HYDROSILYLATION; MECHANISM;
D O I：
10.1039/b925722e
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Stereoselective Si-O couplings are auspicious processes for the synthesis of both chiral alcohols and chiral silanes. Attractive facets of this theme are currently enjoying a renaissance, and the several significant contributions are summarised in this Emerging Area.
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页码：1497 / 1504
页数：8
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