Transformation of a metal-organic framework from the NbO to PtS net

被引：169

作者：

Chen, BL ^{[1
]}

Ockwig, NW

Fronczek, FR

Contreras, DS

Yaghi, OM

机构：

[1] Univ Texas, Dept Chem, Edinburg, TX 78541 USA

[2] Univ Michigan, Dept Chem, Mat Design & Discovery Grp, Ann Arbor, MI 48109 USA

[3] Louisiana State Univ, Dept Chem, Baton Rouge, LA 70803 USA

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 02期

关键词：

D O I：

10.1021/ic048612y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two metal-organic frameworks (MOFs), MOF-501 and MOF-502, respectively, formulated as Co-2(BPTC)(H2O)(5)(.)G(x), and Co-2(BPTC)-(H2O)(DMF)(2)(.)G(x) (BPTC = 3,3',5,5'-biphenyltetracarboxylate; G = guest molecules), have been synthesized and structurally characterized, and their topologies were found to be based on the NbO (MOF-501) and PtS (MOF-502) nets. Heating MOF-501 in solution results in the more thermodynamically favored MOF-502.

引用

页码：181 / 183

页数：3

共 18 条

[1] TOPOLOGICAL REARRANGEMENT WITHIN A SINGLE-CRYSTAL FROM A HONEYCOMB [CD(CN)2]N3D NET TO A DIAMOND NET [J].