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FTIR and thermodynamic study of Pakistani and international crude oils in 1,4-dioxane
被引:2
|作者:
Masood, Summyia
[1
]
Saeed, Rehana
[1
]
Ali, Mehwish
[1
]
Bagum, Samreen
[1
]
Ashfaq, Maria
[1
]
Khan, Sameera Razi
[2
]
机构:
[1] Univ Karachi, Dept Chem, Karachi 75270, Pakistan
[2] Fed Urdu Univ Arts Sci & Technol, Dept Chem, Karachi, Pakistan
关键词:
1;
4-dioxane;
API gravity;
crude oil;
FTIR;
thermodynamic parameters;
VISCOSITY;
RESIDUES;
D O I:
10.1080/10916466.2016.1273243
中图分类号:
TE [石油、天然气工业];
TK [能源与动力工程];
学科分类号:
0807 ;
0820 ;
摘要:
This paper is the continuation of our previous paper, which concerned the viscosity of crude oils in 1,4-dioxane. In this paper, we present the Fourier Transform Infrared (FTIR) spectroscopy and thermodynamic study of Pakistani and International crude oils. Degree of branching, chain length, and degree of substitution in aromatic by FTIR data were calculated. Thermodynamic parameters viz., energy of activation (E), free energy change of activation (G(*)), latent heat of vaporization (L-v), and entropy change of activation (S-*) have also been evaluated.
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页码:754 / 760
页数:7
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