Developing the NiO/CuTiO3/ZnO Ternary Semiconductor Heterojunction for Harnessing Photocatalytic Activity of Reactive Dye with Enhanced Durability

被引:18
作者
Divya, G. [1 ]
Sivakumar, S. [1 ]
Sakthi, D. [2 ]
Priyadharsan, A. [2 ]
Arun, V. [2 ]
Kavitha, R. [3 ]
Boobas, S. [4 ]
机构
[1] ERK Arts & Sci Coll, Dept Chem, Dharmapuri, Tamil Nadu, India
[2] ERK Arts & Sci Coll, Dept Phys, Dharmapuri, Tamil Nadu, India
[3] Shri Sakthikailassh Womens Coll, Dept Chem, Salem, Tamil Nadu, India
[4] Sri Vasavi Coll Govt Aided, Dept Phys, Erode, Tamil Nadu, India
关键词
NiO; CuTiO3; ZnO; Ternary composites; Reactive orange 30; Photocatalytic efficiency and natural sunlight; DEGRADATION; NANOPARTICLES; CARBON; REMOVAL; PHENOL; WATER; NANOCOMPOSITES; ADSORPTION; MECHANISM; ADSORBENT;
D O I
10.1007/s10904-021-02068-0
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Solar active ternary NiO/CuTiO3/ZnO semiconductor heterojunction were developed by alcoholic dispersion technique. As prepared ternary system and parent photocatalysts were analyze crystalline phase, surface morphology, light absorbance property, electron hole accusation parting and significant functional groups by means of specific physicochemical feature measurements. From the results, enhanced visible light photo mineralization, superior efficiency of charge carriers separation and better photocatalytic degradation of reactive orange 30 were confirmed for ternary NiO/CuTiO3/ZnO semiconductor heterojunction. Hydroxyl radical in the radical trapping experiments confirmed the photocatalytic degradation, which plays an important role in removal of hazardous dye from industrial effluents. This work demonstrates that synergetic effect of CuTiO3 and NiO in which it proves to be a good option for recovering the consumption of visible light of ZnO-based materials in the ternary hybrid conduction bands.
引用
收藏
页码:4480 / 4490
页数:11
相关论文
共 38 条
[1]   Activated lignin-chitosan extruded blends for efficient adsorption of methylene blue [J].
Albadarin, Ahmad B. ;
Collins, Maurice N. ;
Naushad, Mu ;
Shirazian, Saeed ;
Walker, Gavin ;
Mangwandi, C. .
CHEMICAL ENGINEERING JOURNAL, 2017, 307 :264-272
[2]   Synthesis, characterization of curcumin based ecofriendly antimicrobial bio-adsorbent for the removal of phenol from aqueous medium [J].
Alshehri, Saad M. ;
Naushad, Mu. ;
Ahamad, Tansir ;
Alothman, Zeid A. ;
Aldalbahi, Ali .
CHEMICAL ENGINEERING JOURNAL, 2014, 254 :181-189
[3]   Combined modification of a TiO2 photocatalyst with two different carbon forms [J].
Anson-Casaos, Alejandro ;
Tacchini, Ignacio ;
Unzue, Andrea ;
Teresa Martinez, M. .
APPLIED SURFACE SCIENCE, 2013, 270 :675-684
[4]   Heterostructured Nanocomposites of Ag Doped Fe3O4 Embedded in ZnO for Antibacterial Applications and Catalytic Conversion of Hazardous Wastes [J].
Babu, Avis Tresa ;
Sebastian, Meera ;
Manaf, O. ;
Antony, Rosy .
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2020, 30 (06) :1944-1955
[5]   Nanofiltration membranes to reduce phenol concentration in wastewater [J].
Bodalo, A. ;
Gomez, E. ;
Hidalgo, A. M. ;
Gomez, M. ;
Murcia, M. D. ;
Lopez, I. .
DESALINATION, 2009, 245 (1-3) :680-686
[6]   Celastrol-modified TiO2 nanoparticles: effects of celastrol on the particle size and visible-light photocatalytic activity [J].
Chen, Caihua ;
Liu, Quanwen ;
Gao, Shanmin ;
Li, Kai ;
Xu, Hui ;
Lou, Zaizhu ;
Huang, Baibiao ;
Dai, Ying .
RSC ADVANCES, 2014, 4 (24) :12098-12104
[7]   P-N junction mechanism on improved NiO/TiO2 photocatalyst [J].
Chen, Cha-Jung ;
Liao, Chi-Hung ;
Hsu, Kai-Chien ;
Wu, Yi-Ting ;
Wu, Jeffrey C. S. .
CATALYSIS COMMUNICATIONS, 2011, 12 (14) :1307-1310
[8]   Fe3O4/ZnO/Ag3VO4/AgI nanocomposites: Quaternary magnetic photocatalysts with excellent activity in degradation of water pollutants under visible light [J].
Habibi-Yangjeh, Aziz ;
Shekofteh-Gohari, Maryam .
SEPARATION AND PURIFICATION TECHNOLOGY, 2016, 166 :63-72
[9]   Synthesis of CdS/ZnO/graphene composite with high-efficiency photoelectrochemical activities under solar radiation [J].
Han, Weijia ;
Ren, Long ;
Qi, Xiang ;
Liu, Yundan ;
Wei, Xiaolin ;
Huang, Zongyu ;
Zhong, Jianxin .
APPLIED SURFACE SCIENCE, 2014, 299 :12-18
[10]   Synthesis, surface modification and photocatalytic property of ZnO nanoparticles [J].
Hong, R. Y. ;
Li, J. H. ;
Chen, L. L. ;
Liu, D. Q. ;
Li, H. Z. ;
Zheng, Y. ;
Ding, J. .
POWDER TECHNOLOGY, 2009, 189 (03) :426-432