The role of isolated active centres in high-performance bioinspired selective oxidation catalysts

被引：7

作者：

Dzierzak, Joanna ^{[1
]}

Bottinelli, Emanuela ^{[1
]}

Berlier, Gloria ^{[1
]}

Gianotti, Enrica ^{[1
]}

Stulz, Eugen ^{[1
]}

Kowalczyk, Radoslaw Michal ^{[1
]}

Raja, Robert ^{[1
]}

机构：

[1] Univ Southampton, Dept Chem, Southampton SO17 1BJ, Hants, England

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 16期

基金：

英国工程与自然科学研究理事会;

关键词：

IRON; FRAMEWORK; COMPLEXES; METALS;

D O I：

10.1039/b926721b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transition-metal complexes containing amino acids encapsulated within solid supports generate isolated active centres that function as effective selective oxidation catalysts using benign oxidants such as air and display high turnovers and selectivity in industrially significant oxidation reactions.

引用

页码：2805 / 2807

页数：3

共 18 条

[1] ZEOLITE ENCAPSULATED COBALT(II) AND COPPER(II) PERFLUOROPHTHALOCYANINES - SYNTHESIS AND CHARACTERIZATION
BALKUS, KJ
GABRIELOV, AG
BELL, SL
BEDIOUI, F
ROUE, L
DEVYNCK, J
[J]. INORGANIC CHEMISTRY, 1994, 33 (01) : 67 - 72
[2] Structure and reactivity of framework and extraframework iron in Fe-silicalite as investigated by spectroscopic and physicochemical methods
Bordiga, S
Buzzoni, R
Geobaldo, F
Lamberti, C
Giamello, E
Zecchina, A
Leofanti, G
Petrini, G
Tozzola, G
Vlaic, G
[J]. JOURNAL OF CATALYSIS, 1996, 158 (02) : 486 - 501
[3] DZIERZAK J, 2009, Patent No. 033510018099
[4] Solvent-free oxidation of primary alcohols to aldehydes using Au-Pd/TiO2 catalysts
Enache, DI
Edwards, JK
Landon, P
Solsona-Espriu, B
Carley, AF
Herzing, AA
Watanabe, M
Kiely, CJ
Knight, DW
Hutchings, GJ
[J]. SCIENCE, 2006, 311 (5759) : 362 - 365
[5] Enantioselective organocatalysis
Gaunt, Matthew J.
Johansson, Carin C. C.
McNally, Andy
Vo, Ngoc T.
[J]. DRUG DISCOVERY TODAY, 2007, 12 (1-2) : 8 - 27
[6] Geometry and framework interactions of zeolite-encapsulated copper(II)-histidine complexes
Grommen, R
Manikandan, P
Gao, Y
Shane, T
Shane, JJ
Schoonheydt, RA
Weckhuysen, BM
Goldfarb, D
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (46) : 11488 - 11496
[7] ENVIRONMENTS OF IRON IN FE-SILICATES SYNTHESIZED BY THE RAPID CRYSTALLIZATION METHOD
INUI, T
NAGATA, H
TAKEGUCHI, T
IWAMOTO, S
MATSUDA, H
INOUE, M
[J]. JOURNAL OF CATALYSIS, 1993, 139 (02) : 482 - 489
[8] Metals coordinate protein-protein interactions
Kerman, Kagan
Kraatz, Heinz-Bernhard
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (35) : 6522 - 6524
[9] LIN DH, 1989, STUD SURF SCI CATAL, V49, P1431
[10] Immobilized complexes of metals with amino acid ligands -: A first step toward the development of new biomimetic catalysts
Luechinger, M
Kienhöfer, A
Pirngruber, GD
[J]. CHEMISTRY OF MATERIALS, 2006, 18 (05) : 1330 - 1336

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