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A uranyl phosphonate framework with a temperature-induced order-disorder transition and temperature-correlated photoluminescence
被引:18
作者:
Wang, Yi
[1
]
Wang, Xiangxiang
[2
,3
]
Zhang, Dongya
[1
]
Zhou, Fan
[1
]
Gui, Daxiang
[2
,3
]
Zheng, Tao
[1
]
Li, Jiansheng
[1
]
Chai, Zhifang
[2
,3
]
Wang, Shuao
[2
,3
]
机构:
[1] Nanjing Univ Sci & Technol, Sch Environm & Biol Engn, Nanjing 210094, Jiangsu, Peoples R China
[2] Soochow Univ, State Key Lab Radiat Med & Protect, Sch Radiol & Interdisciplinary Sci RAD 10, Suzhou 215123, Peoples R China
[3] Soochow Univ, Collaborat Innovat Ctr Radiat Med Jiangsu Higher, Suzhou 215123, Peoples R China
基金:
中国博士后科学基金;
美国国家科学基金会;
关键词:
METAL-ORGANIC FRAMEWORKS;
SINGLE-CRYSTAL;
STRUCTURAL TRANSFORMATION;
PHASE-TRANSITION;
CATALYZED TRANSFORMATION;
COORDINATION POLYMERS;
PROTON CONDUCTION;
REVERSIBLE SCSC;
LUMINESCENT;
BEHAVIOR;
D O I:
10.1039/c8ce00450a
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
A uranyl phosphonate framework, (UO2)(2).1,3-pbp)(H2O)(2)center dot 2H(2)O (UPF-1) (1,3-pbp = 1,3-phenylenebis(phosphonic acid)), experiences a thermally induced order-disorder transition, leading to a negative linear correlation between the photoluminescence intensity and temperature, and may find application as a luminescent thermometer.
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页码:3153 / 3157
页数:5
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