A uranyl phosphonate framework with a temperature-induced order-disorder transition and temperature-correlated photoluminescence

被引：18

作者：

Wang, Yi ^{[1
]}

Wang, Xiangxiang ^{[2
,3
]}

Zhang, Dongya ^{[1
]}

Zhou, Fan ^{[1
]}

Gui, Daxiang ^{[2
,3
]}

Zheng, Tao ^{[1
]}

Li, Jiansheng ^{[1
]}

Chai, Zhifang ^{[2
,3
]}

Wang, Shuao ^{[2
,3
]}

机构：

[1] Nanjing Univ Sci & Technol, Sch Environm & Biol Engn, Nanjing 210094, Jiangsu, Peoples R China

[2] Soochow Univ, State Key Lab Radiat Med & Protect, Sch Radiol & Interdisciplinary Sci RAD 10, Suzhou 215123, Peoples R China

[3] Soochow Univ, Collaborat Innovat Ctr Radiat Med Jiangsu Higher, Suzhou 215123, Peoples R China

来源：

CRYSTENGCOMM | 2018年 / 20卷 / 23期

基金：

中国博士后科学基金; 美国国家科学基金会;

关键词：

METAL-ORGANIC FRAMEWORKS; SINGLE-CRYSTAL; STRUCTURAL TRANSFORMATION; PHASE-TRANSITION; CATALYZED TRANSFORMATION; COORDINATION POLYMERS; PROTON CONDUCTION; REVERSIBLE SCSC; LUMINESCENT; BEHAVIOR;

D O I：

10.1039/c8ce00450a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A uranyl phosphonate framework, (UO2)(2).1,3-pbp)(H2O)(2)center dot 2H(2)O (UPF-1) (1,3-pbp = 1,3-phenylenebis(phosphonic acid)), experiences a thermally induced order-disorder transition, leading to a negative linear correlation between the photoluminescence intensity and temperature, and may find application as a luminescent thermometer.

引用

页码：3153 / 3157

页数：5

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