A uranyl phosphonate framework with a temperature-induced order-disorder transition and temperature-correlated photoluminescence

被引：18
作者：
Wang, Yi [1 ]
Wang, Xiangxiang [2 ,3 ]
Zhang, Dongya [1 ]
Zhou, Fan [1 ]
Gui, Daxiang [2 ,3 ]
Zheng, Tao [1 ]
Li, Jiansheng [1 ]
Chai, Zhifang [2 ,3 ]
Wang, Shuao [2 ,3 ]
机构：
[1] Nanjing Univ Sci & Technol, Sch Environm & Biol Engn, Nanjing 210094, Jiangsu, Peoples R China
[2] Soochow Univ, State Key Lab Radiat Med & Protect, Sch Radiol & Interdisciplinary Sci RAD 10, Suzhou 215123, Peoples R China
[3] Soochow Univ, Collaborat Innovat Ctr Radiat Med Jiangsu Higher, Suzhou 215123, Peoples R China
来源：
CRYSTENGCOMM | 2018年 / 20卷 / 23期
基金：
中国博士后科学基金; 美国国家科学基金会;
关键词：
METAL-ORGANIC FRAMEWORKS; SINGLE-CRYSTAL; STRUCTURAL TRANSFORMATION; PHASE-TRANSITION; CATALYZED TRANSFORMATION; COORDINATION POLYMERS; PROTON CONDUCTION; REVERSIBLE SCSC; LUMINESCENT; BEHAVIOR;
D O I：
10.1039/c8ce00450a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A uranyl phosphonate framework, (UO2)(2).1,3-pbp)(H2O)(2)center dot 2H(2)O (UPF-1) (1,3-pbp = 1,3-phenylenebis(phosphonic acid)), experiences a thermally induced order-disorder transition, leading to a negative linear correlation between the photoluminescence intensity and temperature, and may find application as a luminescent thermometer.
引用
收藏
页码：3153 / 3157
页数：5
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