First catalytic dihydroamination of a phosphaalkyne. Crystal and molecular structure of trans-[PdCl2{P(PriNH)2CH2But}2]

被引：5
作者：
Cloke, FGN [1 ]
Hitchcock, PB [1 ]
Nixon, JF [1 ]
Wilson, DJ [1 ]
机构：
[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 23期
关键词：
D O I：
10.1039/b007512o
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Treatment of a dichloromethane solution of (BuCP)-C-t, containing a catalytic amount of TiCl4, with an excess of the primary amines RNH2 (R = Pr-i, Bu-t) quantitatively affords the corresponding bis-dialkylaminophosphine P((BuNH)-N-t)(2)- CH2But. P((PrNH)-N-i)(2)CH2But is structurally characterised by a single crystal X-ray diffraction study of its bis-trans-PdCl2 complex.
引用
收藏
页码：2387 / 2388
页数：2
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