First catalytic dihydroamination of a phosphaalkyne. Crystal and molecular structure of trans-[PdCl2{P(PriNH)2CH2But}2]

被引：5

作者：

Cloke, FGN ^{[1
]}

Hitchcock, PB ^{[1
]}

Nixon, JF ^{[1
]}

Wilson, DJ ^{[1
]}

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 23期

关键词：

D O I：

10.1039/b007512o

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of a dichloromethane solution of (BuCP)-C-t, containing a catalytic amount of TiCl4, with an excess of the primary amines RNH2 (R = Pr-i, Bu-t) quantitatively affords the corresponding bis-dialkylaminophosphine P((BuNH)-N-t)(2)- CH2But. P((PrNH)-N-i)(2)CH2But is structurally characterised by a single crystal X-ray diffraction study of its bis-trans-PdCl2 complex.

引用

页码：2387 / 2388

页数：2

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