Electron paramagnetic study on radical scavenging properties of ceria nanoparticles

被引:80
作者
Babu, Suresh
Velez, Anthony
Wozniak, Krzysztof
Szydlowska, Jadwiga
Seal, Sudipta [1 ]
机构
[1] Univ Cent Florida, Adv Mat Proc & Anal Ctr, Dept Mech Mat & Aerosp Engn, Orlando, FL 32816 USA
[2] Univ Warsaw, Dept Chem, PL-00325 Warsaw, Poland
关键词
D O I
10.1016/j.cplett.2007.06.026
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ultrafine ceria nanoparticles in the size regime of 3-5 nm were synthesized by chemical methods. The oxygen free radical scavenging properties of ceria nanoparticle was studied using electron paramagnetic resonance technique at the concentrations of 1 mM and 10 mu M in the presence of a spin trap. The hydroxyl radical scavenging properties of ceria nanoparticles were found to vary, depending on the concentrations. At lower concentration the catalytic effect was found to be better compared to that at higher concentration, presumably due to the agglomeration at higher concentrations. (c) 2007 Published by Elsevier B.V.
引用
收藏
页码:405 / 408
页数:4
相关论文
共 22 条
  • [1] DESIGN OF MODIFIED PYRROLINE N-OXIDE DERIVATIVES AS SPIN TRAPS SPECIFIC FOR HYDROXYL RADICAL
    ARYA, P
    STEPHENS, JC
    GRILLER, D
    POU, S
    RAMOS, CL
    POU, WS
    ROSEN, GM
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (08) : 2297 - 2301
  • [2] SPIN TRAPPING - ELECTRON-SPIN-RESONANCE PARAMETERS OF SPIN ADDUCTS
    BUETTNER, GR
    [J]. FREE RADICAL BIOLOGY AND MEDICINE, 1987, 3 (04) : 259 - 303
  • [3] Rare earth nanoparticles prevent retinal degeneration induced by intracellular peroxides
    Chen, Junping
    Patil, Swanand
    Seal, Sudipta
    McGinnis, James F.
    [J]. NATURE NANOTECHNOLOGY, 2006, 1 (02) : 142 - 150
  • [4] Improved method for EPR detection of DEPMPO-superoxide radicals by liquid nitrogen freezing
    Dambrova, M
    Baumane, L
    Kalvinsh, I
    Wikberg, JES
    [J]. BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS, 2000, 275 (03) : 895 - 898
  • [5] Size dependency variation in lattice parameter and valency states in nanocrystalline cerium oxide
    Deshpande, S
    Patil, S
    Kuchibhatla, SVNT
    Seal, S
    [J]. APPLIED PHYSICS LETTERS, 2005, 87 (13) : 1 - 3
  • [6] Effect of particle size on the photocatalytic activity of nanoparticulate zinc oxide
    Dodd, A. C.
    McKinley, A. J.
    Saunders, M.
    Tsuzuki, T.
    [J]. JOURNAL OF NANOPARTICLE RESEARCH, 2006, 8 (01) : 43 - 51
  • [7] EPR study of the photoassisted formation of radicals on CeO2 nanoparticles employed for toluene photooxidation
    Hernández-Alonso, MD
    Hungría, AB
    Martínez-Arias, A
    Fernández-García, M
    Coronado, JM
    Conesa, JC
    Soria, J
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2004, 50 (03) : 167 - 175
  • [8] Steam reforming of ethanol over Pt/ceria with co-fed hydrogen
    Jacobs, Gary
    Keogh, Robert A.
    Davis, Burtron H.
    [J]. JOURNAL OF CATALYSIS, 2007, 245 (02) : 326 - 337
  • [9] JINSHENG W, 1998, J RARE EARTH, V16, P46
  • [10] Jones CM, 2003, BIOCHEM SOC T, V31, P1337