Anionic collagen: Polymer composites with improved dielectric and rheological properties

被引:37
作者
Goissis, G
Piccirili, L
Goes, JC
Plepis, AMD
Das-Gupta, DK
机构
[1] Univ Sao Paulo, Inst Quim, Dept Quim & Fis Mol, BR-13560 Sao Paulo, Brazil
[2] Univ Coll N Wales, Sch Elect Engn, Bangor, Gwynedd, Wales
关键词
anionic collagen; vinylidene fluoride-trifluorethylene; rhamsan; composites; properties;
D O I
10.1046/j.1525-1594.1998.06109.x
中图分类号
R318 [生物医学工程];
学科分类号
0831 ;
摘要
This work describes the preparation and characterization of anionic collagen composites with rhamsan and vinylidene fluoride-trifluorethylene with improved rheological and dielectric properties without loss of collagen secondary structure with an interaction occurring between both macromolecules of the composites. On a comparative basis, the force needed for the extrusion of anionic collagen:rhamsan composites was in the range from 0.088 to 0.080 J compared to that for collagen of 0.189 J. Anionic collagen:vinylidene fluoride-trifluorethylene composites were characterized, in the case of the 1:1 composite, by a pyroelectric coefficient of 1.89 x 10(-4) cm(-2) K-1, which was significantly higher than those determined under the same conditions for native anionic collagen and vinylidene fluoride-trifluorethylene.
引用
收藏
页码:203 / 209
页数:7
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