Glycidol syntheses and valorizations: Boosting the glycerol biorefinery

被引：15

作者：

Prete, Prisco ^{[1
]}

Cespi, Daniele ^{[2
,3
,4
]}

Passarini, Fabrizio ^{[2
,3
,4
]}

Capacchione, Carmine ^{[1
]}

Proto, Antonio ^{[1
]}

Cucciniello, Raffaele ^{[1
]}

机构：

[1] Univ Salerno, Dept Chem & Biol Adolfo Zambelli, Via Giovanni Paolo II 132, I-84084 Fisciano, SA, Italy

[2] Univ Bologna, Dept Ind Chem Toso Montanari, Viale Risorgimento 4, I-40136 Bologna, Italy

[3] Univ Bologna, Interdept Ctr Ind Res Renewable Sources Environm, Via Anghera 22, 47921 Rimini, Italy

[4] Alma Mater Studiorum Univ Bologna, Ctr Chem Catalysis C3, Viale Risorgimento 4, Bologna, Italy

来源：

CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY | 2022年 / 35卷

关键词：

VALUE-ADDED PRODUCT; ALLYL ALCOHOL; HYDROGENOLYSIS; CONVERSION; 1,3-PROPANEDIOL; CARBONATE; CATALYSTS; EPOXIDES; CARBONYLATION; POLYGLYCIDOL;

D O I：

10.1016/j.cogsc.2022.100624

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of bio-based functional molecules and their further conversion to value-added products are among the most investigated research fields within the green chemistry community. In this work, we review the preparation of biobased glycidol and its use as starting material for other chemicals. Herein, we discuss the catalytic approach for the synthesis of several classes of glycidol-derived organics characterized by relevant industrial applications. In detail, glycidol conversion to 1,2 and 1,3-propanediol, glycerol carbonate, solketal, monoalkyl glyceryl ethers, and polymers is reported and future perspectives in this context are proposed.

引用

页数：9

共 80 条

[1] One-pot synthesis of glycidol from glycerol and dimethyl carbonate over KF/sepiolite catalyst [J].