Exposed {001} facet of anatase TiO2 nanocrystals in Ag/TiO2 catalysts for boosting catalytic soot combustion: The facet-dependent activity

Herein, the nanocatalysts of Ag nanoparticles (NPs) coated on anatase TiO2-n% nanocrystals with co-exposed {1 0 1} and {0 0 1} facets were elaborately constructed by the urea-induced hydrothermal method. The ratios (n%) of exposed {001} facet in TiO2 nanocrystals are adjusted in the range of 8-79%. Ag/TiO2-n% catalysts exhibited excellent the exposed {0 0 1} facet-dependent catalytic activity during soot combustion. Ag/TiO2-79% catalyst shows the highest catalytic activity (T-50 = 364 degrees C, TOF = 0.174 h(-1) at 310 degrees C) and the lowest apparent activation energy (84 kJ mol(-1)). Combination insitu Raman spectra and density functional theory (DFT) calculations, the catalytic mechanism is proposed: the active sites locate at the interface between Ag and {0 0 1} facet of TiO2-n% nanocrystal, and the synergy effect of coordinatively unsaturated Ti-5c and adjacent Ag atoms boosts the key step of O-2 activation. It highlights an effective strategy to develop high-efficient catalysts by the crystal facet engineering of metal oxides during oxidation reaction. (C) 2021 Elsevier Inc. All rights reserved.