A Non-Doped Phosphorescent Organic Light-Emitting Device with Above 31% External Quantum Efficiency

被引:150
作者
Wang, Qi [1 ,2 ,3 ,4 ]
Oswald, Iain W. H. [5 ]
Yang, Xiaolong [4 ]
Zhou, Guijiang [4 ]
Jia, Huiping [1 ,2 ]
Qiao, Qiquan [3 ]
Chen, Yonghua [6 ]
Hoshikawa-Halbert, Jason [7 ]
Gnade, Bruce E. [1 ,2 ]
机构
[1] Univ Texas Dallas, Dept Mat Sci & Engn, Richardson, TX 75083 USA
[2] Univ Texas Dallas, Erik Jonsson Sch Engn & Comp Sci, Richardson, TX 75083 USA
[3] S Dakota State Univ, Dept Elect Engn & Comp Sci, Coll Engn, Brookings, SD 57007 USA
[4] Xi An Jiao Tong Univ, Dept Appl Chem, Xian 710049, Peoples R China
[5] Univ Texas Dallas, Dept Chem, Richardson, TX 75083 USA
[6] Wake Forest Univ, Ctr Nanotechnol & Mol Mat, Dept Phys, Winston Salem, NC 27106 USA
[7] Kyoto Univ, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan
基金
美国国家科学基金会;
关键词
FUNCTIONALIZED BETA-DIKETONATE; TRIPLET-TRIPLET ANNIHILATION; LOW-DRIVING-VOLTAGE; PLATINUM(II) COMPLEXES; ROLL-OFF; TRANSPORT MATERIAL; IRIDIUM COMPLEXES; ENERGY-LEVEL; THIN-FILMS; DIODES;
D O I
10.1002/adma.201402947
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) The demonstrated square-planar Pt(II)-complex has reduced triplet-triplet quenching and therefore a near unity quantum yield in the neat thin film. A non-doped phosphorescent organic light-emitting diode (PhOLED) based on this emitter achieves (31.1 ± 0.1)% external quantum efficiency without any out-coupling, which shows that a non-doped PhOLED can be comparable in efficiency to the best doped devices with very complicated device structures. © 2014 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:8107 / 8113
页数:7
相关论文
共 89 条
  • [1] Nearly 100% internal phosphorescence efficiency in an organic light-emitting device
    Adachi, C
    Baldo, MA
    Thompson, ME
    Forrest, SR
    [J]. JOURNAL OF APPLIED PHYSICS, 2001, 90 (10) : 5048 - 5051
  • [2] Transient analysis of organic electrophosphorescence. II. Transient analysis of triplet-triplet annihilation
    Baldo, MA
    Adachi, C
    Forrest, SR
    [J]. PHYSICAL REVIEW B, 2000, 62 (16) : 10967 - 10977
  • [3] Activating efficient phosphorescence from purely organic materials by crystal design
    Bolton, Onas
    Lee, Kangwon
    Kim, Hyong-Jun
    Lin, Kevin Y.
    Kim, Jinsang
    [J]. NATURE CHEMISTRY, 2011, 3 (03) : 205 - 210
  • [4] Tuning the colour and efficiency in OLEDs by using amorphous or polycrystalline emitting layers
    Brulatti, Pierpaolo
    Fattori, Valeria
    Muzzioli, Sara
    Stagni, Stefano
    Mazzeo, Paolo Pio
    Braga, Dario
    Maini, Lucia
    Milita, Silvia
    Cocchi, Massimo
    [J]. JOURNAL OF MATERIALS CHEMISTRY C, 2013, 1 (09) : 1823 - 1831
  • [5] Bright, saturated, red-to-yellow organic light-emitting devices based on polarization-induced spectral shifts
    Bulovic, V
    Shoustikov, A
    Baldo, MA
    Bose, E
    Kozlov, VG
    Thompson, ME
    Forrest, SR
    [J]. CHEMICAL PHYSICS LETTERS, 1998, 287 (3-4) : 455 - 460
  • [6] High-Efficiency Solution-Processed Small Molecule Electrophosphorescent Organic Light-Emitting Diodes
    Cai, Min
    Xiao, Teng
    Hellerich, Emily
    Chen, Ying
    Shinar, Ruth
    Shinar, Joseph
    [J]. ADVANCED MATERIALS, 2011, 23 (31) : 3590 - +
  • [7] Capelli R, 2010, NAT MATER, V9, P496, DOI [10.1038/NMAT2751, 10.1038/nmat2751]
  • [8] Platinum(II) complexes with pyridyl azolate-based chelates: Synthesis, structural characterization, and tuning of photo- and electrophosphorescence
    Chang, SY
    Kavitha, J
    Li, SW
    Hsu, CS
    Chi, Y
    Yeh, YS
    Chou, PT
    Lee, GH
    Carty, AJ
    Tao, YT
    Chien, CH
    [J]. INORGANIC CHEMISTRY, 2006, 45 (01) : 137 - 146
  • [9] Enhancing the efficiency of simplified red phosphorescent organic light emitting diodes by exciton harvesting
    Chang, Y-L
    Wang, Z. B.
    Helander, M. G.
    Qiu, J.
    Puzzo, D. P.
    Lu, Z. H.
    [J]. ORGANIC ELECTRONICS, 2012, 13 (05) : 925 - 931
  • [10] Platinum Phosphors Containing an Aryl-modified β-Diketonate: Unusual Effect of Molecular Packing on Photo- and Electroluminescence
    Chen, Chin-Hsien
    Wu, Fang-Iy
    Tsai, Yin-Yen
    Cheng, Chien-Hong
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (16) : 3150 - 3158