Fabrication and high radiation-resistant properties of functionalized carbon nanotube reinforced novolac epoxy resin nanocomposite coatings

被引:9
作者
Chang, Shuquan [1 ]
Li, Jin [1 ]
Han, Wei [1 ]
Zhang, Zheng [1 ]
Chang, Ling [1 ]
Chen, Wei [1 ]
Li, Zheng [1 ]
Dai, Yaodong [1 ]
Chen, Da [1 ]
机构
[1] Nanjing Univ Aeronaut & Astronaut, Jiangsu Engn Lab Nucl Energy Equipment Mat, Coll Mat Sci & Technol, Nanjing 210016, Jiangsu, Peoples R China
基金
中国国家自然科学基金;
关键词
GAMMA-IRRADIATION; DEGRADATION RESISTANCE; STABILITY; POLYETHYLENE; ENVIRONMENT; COMPOSITES; POLYMERS; SYSTEMS; PLANTS; FILMS;
D O I
10.1039/c6ra09255a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Carboxyl-functionalized multi-walled carbon nanotube (c-MWCNT) reinforced novolac epoxy resin composite coatings with high radiation-resistant performance were successfully fabricated and investigated. Well-dispersed c-MWCNTs were prepared via a gamma radiation method. The microstructure, abrasion resistance and impact resistance of the composite coatings with varying content of c-MWCNTs (0 wt%, 0.1 wt%, 0.26 wt%, 0.5 wt%, and 0.75 wt%, 1 wt%) were studied in detail via high-dose Co-60 gamma radiation (6000 kGy). All of the results reveal that the addition of c-MWCNTs obviously enhanced the radiation-resistance and comprehensive performance of the composite coatings. 0.75 wt% c-MWCNTs was the optimum content. The process and mechanism were generally discussed. The resulting composite coatings can be widely applied in nuclear power plants and other radiation environments.
引用
收藏
页码:58296 / 58301
页数:6
相关论文
共 34 条
[1]   Materials challenges for nuclear systems [J].
Allen, Todd ;
Busby, Jeremy ;
Meyer, Mitch ;
Petti, David .
MATERIALS TODAY, 2010, 13 (12) :14-23
[2]   Stability of Grafted Polymer Nanoscale Films toward Gamma Irradiation [J].
Borodinov, Niko Lay ;
Giarnmarco, James ;
Patel, Neil ;
Agarwal, Anuradha ;
O'Donnell, Katie R. ;
Kucera, Courtney J. ;
Jacobsohn, Luiz G. ;
Luzinov, Igor .
ACS APPLIED MATERIALS & INTERFACES, 2015, 7 (34) :19455-19465
[3]   Iodine-paint interactions during nuclear reactor severe accidents [J].
Bosland, L. ;
Dickinson, S. ;
Glowa, G. A. ;
Herranz, L. E. ;
Kim, H. C. ;
Powers, D. A. ;
Salay, M. ;
Tietze, S. .
ANNALS OF NUCLEAR ENERGY, 2014, 74 :184-199
[4]   Stability of polymers under ionising radiation: The many faces of radiation interactions with polymers [J].
Davenas, J ;
Stevenson, I ;
Celette, N ;
Cambon, S ;
Gardette, JL ;
Rivaton, A ;
Vignoud, L .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 2002, 191 :653-661
[5]   Carbon Nanotubes: Present and Future Commercial Applications [J].
De Volder, Michael F. L. ;
Tawfick, Sameh H. ;
Baughman, Ray H. ;
Hart, A. John .
SCIENCE, 2013, 339 (6119) :535-539
[6]   Radiochemical ageing of an amine cured epoxy network. Part II: kinetic modelling [J].
Devanne, T ;
Bry, A ;
Raguin, N ;
Sebban, M ;
Palmas, P ;
Audouin, L ;
Verdu, J .
POLYMER, 2005, 46 (01) :237-242
[7]   Degradation of epoxy coatings under gamma irradiation [J].
Djouani, F. ;
Zahra, Y. ;
Fayolle, B. ;
Kuntz, M. ;
Verdu, J. .
RADIATION PHYSICS AND CHEMISTRY, 2013, 82 :54-62
[8]   Effects of WO3 Particle Size in WO3/Epoxy Resin Radiation Shielding Material [J].
Dong Yu ;
Chang Shu-Quan ;
Zhang Hong-Xu ;
Ren Chao ;
Kang Bin ;
Dai Ming-Zhu ;
Dai Yao-Dong .
CHINESE PHYSICS LETTERS, 2012, 29 (10)
[9]   Degradation of modified carbon black/epoxy nanocomposite coatings under ultraviolet exposure [J].
Ghasemi-Kahrizsangi, Ahmad ;
Shariatpanahi, Homeira ;
Neshati, Jaber ;
Akbarinezhad, Esmaeil .
APPLIED SURFACE SCIENCE, 2015, 353 :530-539
[10]   Improving the UV degradation resistance of epoxy coatings using modified carbon black nanoparticles [J].
Ghasemi-Kahrizsangi, Ahmad ;
Neshati, Jaber ;
Shariatpanahi, Homeira ;
Akbarinezhad, Esmaeil .
PROGRESS IN ORGANIC COATINGS, 2015, 85 :199-207