Rh(I)-Catalyzed Decarboxylative Transformations of Arenecarboxylic Acids: Ligand- and Reagent-Controlled Selectivity toward Hydrodecarboxylation or Heck-Mizoroki Products

被引：115

作者：

Sun, Zhong-Ming ^{[1
]}

Zhang, Jing ^{[1
]}

Zhao, Pinjing ^{[1
]}

机构：

[1] N Dakota State Univ, Dept Chem & Mol Biol, Fargo, ND 58105 USA

来源：

ORGANIC LETTERS | 2010年 / 12卷 / 05期

基金：

美国国家科学基金会;

关键词：

AROMATIC CARBOXYLIC-ACIDS; CROSS-COUPLING REACTION; CATALYZED PROTODECARBOXYLATION; CONJUGATE ADDITION; BIARYL SYNTHESIS; BENZOIC-ACIDS; ARYL HALIDES; ARENE; OLEFINATION; ESTERS;

D O I：

10.1021/ol100001b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A Rh(I)-based catalyst system has been developed to promote three types of decarboxylative transformations of arenecarboxylic acids: (1) hydrodecarboxylation, (2) Heck-Mizoroki olefination, and (3) conjugate addition. Scopes of reactions (1) and (2) were studied, and the ligand and reagent dependence of selectivity was explored.

引用

页码：992 / 995

页数：4

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