Robust and Versatile Cu(I) metal frameworks as potential catalysts for azide-alkyne cycloaddition reactions: Review

被引：46
作者：
Saini, Parveen [1 ]
Sonika [1 ]
Singh, Gurjaspreet [2 ]
Kaur, Gurpreet [3 ]
Singh, Jandeep [1 ]
Singh, Harminder [1 ]
机构：
[1] Lovely Profess Univ, Sch Chem Engn & Phys Sci, Phagwara 144411, Punjab, India
[2] Panjab Univ, Dept Chem, Chandigarh 160014, India
[3] Panjab Univ, Ctr Adv STudies Chem, Chandigarh 160014, India
来源：
MOLECULAR CATALYSIS | 2021年 / 504卷
关键词：
Azide-alkyne cycloaddition; CuAAC; Click chemistry; Cu (I) catalyst; Triazole formation; Catalysis;
D O I：
10.1016/j.mcat.2021.111432
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The use of ?Click Reaction? for Cu(I) catalyzed azide?alkyne cycloaddition (CuAAC) has emerged as one of the most powerful tools for the synthesis of library of organic molecules having a wide range of applications. The approach is highly stereoselective that involves the formation of 1,4?disubstituted 1,2,3?triazole derivatives by the combination of diverse structural entities in the presence of Cu(I) as catalyst. There are numerous synthetic Cu (I) complexes with different ligands bound in diverse molecular framework with potential to act as catalyst to stitch organic azide to alkyne producing 1,4-di-substituted products. This review emphasizes on those versatile Cu (I) complexes having tailoring capability similar to those available commercially.
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页数：14
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