Interfacial rheology of polyelectrolytes and polymer monolayers at the air-water interface

被引：86

作者：

Langevin, Dominique ^{[1
,2
]}

Monroy, Francisco ^{[3
]}

机构：

[1] CNRS, Phys Solides Lab, UMR 8502, F-91405 Orsay, France

[2] Univ Paris 11, F-91405 Orsay, France

[3] Univ Complutense, Dpto Quim Fis 1, E-28040 Madrid, Spain

来源：

CURRENT OPINION IN COLLOID & INTERFACE SCIENCE | 2010年 / 15卷 / 04期

关键词：

Spread polymer monolayers; Adsorbed polyelectrolyte-surfactant layers; Surface rheology; OPPOSITELY CHARGED POLYELECTROLYTES; SURFACE LIGHT-SCATTERING; MOLECULAR-WEIGHT DEPENDENCE; SODIUM DODECYL-SULFATE; AIR/WATER INTERFACE; DODECYLTRIMETHYLAMMONIUM BROMIDE; DILATIONAL VISCOELASTICITY; POLY(METHYL METHACRYLATE); POLY(ETHYLENE OXIDE); ADSORPTION FILMS;

D O I：

10.1016/j.cocis.2010.02.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this review, we describe interfacial rheology studies of polymer monolayers at the air-water interface. Since polyelectrolytes are usually soluble in water, the formation of surface monolayers requires the presence of a surfactant of opposite charge. The first part of the review is dedicated to these mixed monolayers. The second part is related to neutral monolayers that can be either adsorbed or deposited at the interface. Interfacial rheology studies of these systems are still scarce, despite a considerable interest: insoluble polymer monolayers in two dimensions are suitable model systems for the tests of polymer theories in two dimensions, such as and glass transition. The rheology of soluble polymer monolayers has important connections with the dynamic properties of dispersions stabilized with these polymers. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：283 / 293

页数：11

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