Large piezoelectric properties in KNN-based lead-free single crystals grown by a seed-free solid-state crystal growth method

被引:21
作者
Yang, Jie [1 ,2 ]
Zhang, Faqiang [1 ]
Yang, Qunbao [1 ]
Liu, Zhifu [1 ]
Li, Yongxiang [1 ]
Liu, Yun [3 ]
Zhang, Qiming [4 ,5 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Ceram, CAS Key Lab Inorgan Funct Mat & Devices, Shanghai 200050, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100049, Peoples R China
[3] Australian Natl Univ, Res Sch Chem, Canberra, ACT 2601, Australia
[4] Penn State Univ, Dept Elect Engn, University Pk, PA 16802 USA
[5] Penn State Univ, Mat Res Inst, University Pk, PA 16802 USA
基金
中国国家自然科学基金; 澳大利亚研究理事会;
关键词
TEMPLATED GRAIN-GROWTH; FREE CERAMICS; BEHAVIOR; PHASE; EVOLUTION; NA;
D O I
10.1063/1.4948642
中图分类号
O59 [应用物理学];
学科分类号
摘要
We report lead-free single crystals with a nominal formula of (K0.45Na0.55)(0.96)Li0.04NbO3 grown using a simple low-cost seed-free solid-state crystal growth method (SFSSCG). The crystals thus prepared can reach maximum dimensions of 6mm x 5mm x 2mm and exhibit a large piezoelectric coefficient d(33) of 689 pC/N. Moreover, the effective piezoelectric coefficient d(33)*, obtained under a unipolar electric field of 30 kV/ cm, can reach 967 pm/ V. The large piezoelectric response plus the high Curie temperature (T-C) of 432 degrees C indicate that SFSSCG is an effective approach to synthesize high-performance lead-free piezoelectric single crystals. Published by AIP Publishing.
引用
收藏
页数:4
相关论文
共 50 条
  • [21] Growth and properties of Li, Ta modified (K, Na) NbO3 lead-free piezoelectric single crystals
    Huo, Xiaoqing
    Zheng, Limei
    Zhang, Shujun
    Zhang, Rui
    Liu, Gang
    Wang, Rui
    Yang, Bin
    Cao, Wenwu
    Shrout, Thomas R.
    PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, 2014, 8 (01): : 86 - 90
  • [22] Large size lead-free (Na,K)(Nb,Ta)O3 piezoelectric single crystal: growth and full tensor properties
    Zheng, Limei
    Huo, Xiaoqing
    Wang, Rui
    Wang, Junjun
    Jiang, Wenhua
    Cao, Wenwu
    CRYSTENGCOMM, 2013, 15 (38): : 7718 - 7722
  • [23] Composition design and electrical property of a pure K x Na1-x NbO3 single crystal fabricated by the seed-free solid-state crystal growth
    Hao, C. Y.
    Gu, Z. F.
    Cheng, G.
    Li, L.
    Zhang, J. W.
    Song, J. G.
    Yan, Y. F.
    Jiang, M. H.
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2017, 28 (24) : 18357 - 18365
  • [24] Effect of ZrO2 doping on the growth of lead-free piezoelectric 0.75(Bi1/2Na1/2)TiO3-0.25SrTiO3 single crystals by solid-state single crystal growth
    Abbas, Ali
    Le, Phan Gia
    Fisher, John G.
    FERROELECTRICS, 2023, 603 (01) : 52 - 65
  • [25] Giant piezoelectric properties of the [110]-oriented PZT-5H single crystals grown by solid state crystal growth
    Wang, Honghui
    Ma, Ming
    Xia, Song
    Zhang, Nan
    Li, Zhenrong
    JOURNAL OF MATERIALS CHEMISTRY C, 2023, 11 (07) : 2664 - 2671
  • [26] Piezoelectric and ferroelectric properties of lead-free niobium-rich potassium lithium tantalate niobate single crystals
    Li, Jun
    Li, Yang
    Zhou, Zhongxiang
    Guo, Ruyan
    Bhalla, Amar S.
    MATERIALS RESEARCH BULLETIN, 2014, 49 : 206 - 209
  • [27] Orientation dependence of electrical properties of large-sized sodium potassium niobate lead-free single crystals
    Deng, Hao
    Zhao, Xiangyong
    Zhang, Haiwu
    Chen, Chao
    Li, Xiaobing
    Lin, Di
    Ren, Bo
    Jiao, Jie
    Luo, Haosu
    CRYSTENGCOMM, 2014, 16 (13): : 2760 - 2765
  • [28] Dielectric properties in lead-free piezoelectric (Bi0.5Na0.5)TiO3-BaTiO3 single crystals and ceramics
    Chen, C. -S.
    Tu, C. S.
    Chen, P. -Y.
    Ting, Y.
    Chiu, S. -J.
    Hung, C. M.
    Lee, H. -Y
    Wang, S. -F.
    Anthoninappen, J.
    Schmidt, V. H.
    Chien, R. R.
    JOURNAL OF CRYSTAL GROWTH, 2014, 393 : 129 - 133
  • [29] Crystal structure and piezoelectric properties of lead-free epitaxial (K,Na)NbO3 thin films grown on Si substrates
    Tanaka, Kiyotaka
    Kawata, Yoshiyuki
    Kweon, Sang Hyo
    Tan, Goon
    Yoshimura, Takeshi
    Kanno, Isaku
    APPLIED PHYSICS LETTERS, 2022, 121 (17)
  • [30] Phase boundary design and enhanced electrical properties in (Bi0.5Li0.45Ag0.05)(Zr0.98Hf0.02)O3-modified KNN-based lead-free piezoceramic
    He, Bo
    Du, Yi
    Liu, Yang
    Wang, Jiajia
    Liu, Weipeng
    Xu, Huixiang
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2021, 32 (13) : 18240 - 18250