Preparation and characterization of processable electroactive polyaniline-polyvinyl alcohol composite

被引:129
作者
Mirmohseni, A
Wallace, GG
机构
[1] Univ Wollongong, Intelligent Polymer Res Inst, Wollongong, NSW 2522, Australia
[2] Univ Tabriz, Fac Chem, Dept Appl Chem, Polymer Res Technol Lab, Tabriz, Iran
基金
澳大利亚研究理事会;
关键词
conducting polymer composites; polyaniline; water based dispersions;
D O I
10.1016/S0032-3861(03)00242-8
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this paper, the preparation and characterization of polyaniline-polyvinyl alcohol composites is described. The polyaniline composite was synthesized by chemical polymerization of aniline in media containing polyvinyl alcohol (10%, w/w). Oxidation of aniline results in a stable water based polyaniline dispersion, which can be cast to form a mechanically robust film. The electrical conductivity of the films increased with increasing amount of polyaniline to a high value of 2.5 S cm(-1). Cyclic voltammograms revealed that the composite materials are electroactive. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:3523 / 3528
页数:6
相关论文
共 39 条
  • [1] ARMES P, 1989, J CHEM SOC, P88
  • [2] NOVEL POLYANILINE DISPERSIONS USING POLY(VINYL METHYL-ETHER) STABILIZER
    BANERJEE, P
    DIGAR, ML
    BHATTACHARYYA, SN
    MANDAL, BM
    [J]. EUROPEAN POLYMER JOURNAL, 1994, 30 (04) : 499 - 501
  • [3] ELECTRICALLY CONDUCTIVE COMPOSITE OF POLYANILINE AND POLY(P-PHENYLENE DIPHENYL ETHER TEREPHTHALAMIDE)
    BI, XT
    XUE, ZJ
    [J]. POLYMER INTERNATIONAL, 1991, 26 (03) : 151 - 155
  • [4] Pulsed photoconductivity in composite polyaniline-polyvinyl alcohol films
    Bondarenko, VE
    Zhuravleva, TS
    Efimov, ON
    Nikolaeva, GV
    [J]. SYNTHETIC METALS, 1999, 102 (1-3) : 1228 - 1229
  • [5] Methyl cellulose stabilized polyaniline dispersions
    Chattopadhyay, D
    Mandal, BM
    [J]. LANGMUIR, 1996, 12 (06) : 1585 - 1588
  • [6] The dc and ac conductivity of polyaniline-polyvinyl alcohol blends
    Dutta, P
    Biswas, S
    Ghosh, M
    De, SK
    Chatterjee, S
    [J]. SYNTHETIC METALS, 2001, 122 (02) : 455 - 461
  • [7] Polyaniline-poly (vinyl alcohol) conducting composite: material with easy processability and novel application potential
    Gangopadhyay, R
    De, A
    Ghosh, G
    [J]. SYNTHETIC METALS, 2001, 123 (01) : 21 - 31
  • [8] ON THE MECHANISM OF OXIDATIVE POLYMERIZATION OF ANILINE
    GOSPODINOVA, N
    TERLEMEZYAN, L
    MOKREVA, P
    KOSSEV, K
    [J]. POLYMER, 1993, 34 (11) : 2434 - 2437
  • [9] A new route to polyaniline composites
    Gospodinova, N
    Mokreva, P
    Tsanov, T
    Terlemezyan, L
    [J]. POLYMER, 1997, 38 (03) : 743 - 746
  • [10] Thermal and morphological studies on ethylene-vinyl acetate copolymer-polyaniline blends
    Jeevananda, T
    Siddaramaiah
    [J]. THERMOCHIMICA ACTA, 2001, 376 (01) : 51 - 61