Enantioselectivity in the reduction of tricyclic hydroaromatic ketones by baker's yeast

被引：4
|
作者：
Fontana, G
Manitto, P
Speranza, G
Zanzola, S
机构：
[1] Univ Milan, Dipartimento Chim Organ & Ind, I-20133 Milan, Italy
[2] CNR, Ctr Studio Sostanze Organ Nat, I-20133 Milan, Italy
来源：
TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 08期
关键词：
D O I：
10.1016/S0957-4166(98)00111-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three benzo-2-tetralones were hydrogenated to the corresponding alcohols by non-fermenting baker's yeast. Satisfactory yields but modest enantioselectivities were observed. The prevalent enantioform of the benzo-2-tetralol was found to be in agreement with the predictive abstract model previously proposed for the enzymatic hydrogenation of aromatic ring substituted 2-tetralones. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1381 / 1387
页数：7
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