Influence of TiO2 incorporation in HfO2 and Al2O3 based capacitor dielectrics

被引:30
作者
Kukli, Kaupo
Ritala, Mikko
Leskela, Markku
Sundqvist, Jonas
Oberbeck, Lars
Heitmann, Johannes
Schroeder, Uwe
Aarik, Jaan
Aidla, Aleks
机构
[1] Univ Helsinki, Dept Chem, FIN-00014 Helsinki, Finland
[2] Qimonda Dresden GmbH & Co OHG, D-01099 Dresden, Germany
[3] Univ Tartu, Inst Phys, EE-51010 Tartu, Estonia
关键词
atomic layer deposition; dielectric properties; multilayers; nanostructures;
D O I
10.1016/j.tsf.2006.11.049
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Atomic layer deposition was applied to fabricate metal oxide films on planar substrates and also in deep trenches with appreciable step coverage. Atomic layer deposition of Ru electrodes was realized on planar substrates. Electrical and structural behaviour of HfO2-TiO2 and A1(2)O(3)-TiO2 nanolaminates and mixtures as well as Al2O3 films were evaluated. The lowest leakage current densities with the lowest equivalent oxide thickness were achieved in mixed Al2O3-TiO2 films annealed at 700 degrees C, compared to all other films in as-deposited state as well as annealed at 900 degrees C. The highest permittivities in this study were measured on HfO2-TiO2 nanolaminates. (C) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:6447 / 6451
页数:5
相关论文
共 22 条
[11]   Atomic layer deposition and characterization of HfO2 films on noble metal film substrates [J].
Kukli, K ;
Aaltonen, T ;
Aarik, J ;
Lu, J ;
Ritala, M ;
Ferrari, S ;
Hårsta, A ;
Leskelä, M .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (07) :F75-F82
[12]   Properties of Ta2O3-based dielectric nanolaminates deposited by atomic layer epitaxy [J].
Kukli, K ;
Ihanus, J ;
Ritala, M ;
Leskela, M .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (01) :300-306
[13]   Atomic layer deposition chemistry:: Recent developments and future challenges [J].
Leskelä, M ;
Ritala, M .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (45) :5548-5554
[14]   Atomic layer deposition of TiO2 and Al2O3 thin films and nanolaminates [J].
Mitchell, DRG ;
Triani, G ;
Attard, DJ ;
Finnie, KS ;
Evans, PJ ;
Barbé, CJ ;
Bartlett, JR .
SMART MATERIALS AND STRUCTURES, 2006, 15 (01) :S57-S64
[15]   Localization and physical analysis of dielectric weaknesses for state-of-the-art deep trench based DRAM products [J].
Neumann, G ;
Touzel, J ;
Duschl, R .
MICROELECTRONICS RELIABILITY, 2005, 45 (9-11) :1520-1525
[16]   Atomic layer deposition of photocatalytic TiO2 thin films from titanium tetramethoxide and water [J].
Pore, V ;
Rahtu, A ;
Leskelä, M ;
Ritala, M ;
Sajavaara, T ;
Keinonen, J .
CHEMICAL VAPOR DEPOSITION, 2004, 10 (03) :143-148
[18]  
SCHROEDER U, 2006, PHYS TECHNOLOGY HI 3, V1, P126
[19]   Thickness profiles of thin films caused by secondary reactions in flow-type atomic layer deposition reactors [J].
Siimon, H ;
Aarik, J .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1997, 30 (12) :1725-1728
[20]   Impact of titanium addition on film characteristics of HfO2 gate dielectrics deposited by atomic layer deposition -: art. no. 054104 [J].
Triyoso, DH ;
Hegde, RI ;
Zollner, S ;
Ramon, ME ;
Kalpat, S ;
Gregory, R ;
Wang, XD ;
Jiang, J ;
Raymond, M ;
Rai, R ;
Werho, D ;
Roan, D ;
White, BE ;
Tobin, PJ .
JOURNAL OF APPLIED PHYSICS, 2005, 98 (05)