Sol-gel fabrication of lithium-ion microarray battery

被引：46
作者：
Dokko, Kaoru
Sugaya, Jun-ichi
Nakano, Hiroyuki
Yasukawa, Tomoyuki
Matsue, Tomokazu
Kanamura, Kiyoshi
机构：
[1] Tokyo Metropolitan Univ, Dept Appl Chem, Grad Sch Urban Environm Sci, Hachioji, Tokyo 1920397, Japan
[2] Japan Sci & Technol Agcy, CREST, Kawaguchi, Saitama 3320012, Japan
[3] Tohoku Univ, Grad Sch Environm Studies, Aoba Ku, Sendai, Miyagi 9808579, Japan
来源：
ELECTROCHEMISTRY COMMUNICATIONS | 2007年 / 9卷 / 05期
关键词：
lithium batteries; sol-gel; microelectrodes;
D O I：
10.1016/j.elecom.2006.11.025
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Microarray electrodes of LiMn2O4 and Li4/3Ti5/3O4 were prepared on a glass substrate using a sol-gel method. The prepared LiMn2O4 and Li4/3Ti5/3O4 microarray electrodes were characterized with scanning electron microscopy, Raman spectroscopy, and cyclic voltammetry. Using a polymer-gel electrolyte, lithium ion microbattery of Li4/3Ti5/3O4/polymer-gel/LiMn2O4 (cell area: 6.6 x 10(-2) cm(2)) was successfully constructed. The microbattery operated reversibly at 2.5 V, and the discharge capacity was 300 nA h, which corresponded to an energy density of 11 mu W h cm(-2). (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：857 / 862
页数：6
相关论文
共 27 条
  • [1] ELECTROCHEMICAL RESPONSE AT MICROARRAY ELECTRODES IN FLOWING STREAMS AND DETERMINATION OF CATECHOLAMINES
    AOKI, A
    MATSUE, T
    UCHIDA, I
    [J]. ANALYTICAL CHEMISTRY, 1990, 62 (20) : 2206 - 2210
  • [2] A new class of advanced polymer electrolytes and their relevance in plastic-like, rechargeable lithium batteries
    Appetecchi, GB
    Dautzenberg, G
    Scrosati, B
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (01) : 6 - 12
  • [3] Thin-film lithium and lithium-ion batteries
    Bates, JB
    Dudney, NJ
    Neudecker, B
    Ueda, A
    Evans, CD
    [J]. SOLID STATE IONICS, 2000, 135 (1-4) : 33 - 45
  • [4] Preparation of micro-dot electrodes of LiCoO2 and Li4Ti5O12 for lithium micro-batteries
    Dokko, K
    Sugaya, J
    Munakata, H
    Kanamura, K
    [J]. ELECTROCHIMICA ACTA, 2005, 51 (05) : 966 - 971
  • [5] Micro-patterning of LiMn2O4 electrode using sol-gel process for lithium micro-batteries
    Dokko, K
    Sugaya, J
    Munakata, H
    Kanamura, K
    [J]. CHEMISTRY LETTERS, 2005, 34 (07) : 984 - 985
  • [6] SPINEL ANODES FOR LITHIUM-ION BATTERIES
    FERG, E
    GUMMOW, RJ
    DEKOCK, A
    THACKERAY, MM
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (11) : L147 - L150
  • [7] Advanced materials for the 3D microbattery
    Golodnitsky, D
    Yufit, V
    Nathan, M
    Shechtman, I
    Ripenbein, T
    Strauss, E
    Menkin, S
    Peled, E
    [J]. JOURNAL OF POWER SOURCES, 2006, 153 (02) : 281 - 287
  • [8] 3-D microbatteries
    Hart, RW
    White, HS
    Dunn, B
    Rolison, DR
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2003, 5 (02) : 120 - 123
  • [9] A new kind of all-solid-state thin-film-type lithium-ion battery developed by applying a DC high voltage
    Iriyama, Yasutoshi
    Yada, Chihiro
    Abe, Takeshi
    Ogumi, Zenipachi
    Kikuchi, Kenji
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2006, 8 (08) : 1287 - 1291
  • [10] THIN-FILM RECHARGEABLE LI BATTERIES
    JONES, SD
    AKRIDGE, JR
    SHOKOOHI, FK
    [J]. SOLID STATE IONICS, 1994, 69 (3-4) : 357 - 368
123