Fluorine insertion reactions into pre-formed metal oxides

被引：58

作者：

McCabe, Emma E. ^{[1
]}

Greaves, Colin ^{[1
]}

机构：

[1] Univ Birmingham, Sch Chem, Birmingham B15 2TT, W Midlands, England

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2007年 / 128卷 / 04期

基金：

英国工程与自然科学研究理事会;

关键词：

fluorine insertion; oxide-fluorides; transition metal oxide fluorides;

D O I：

10.1016/j.jfluchem.2006.11.008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Fluorine insertion reactions have been shown to be capable of modifying the physical properties of metal oxide materials, as a result of the structural and electronic consequences of fluorine insertion. This has been applied to copper oxide systems and has led to an enhanced understanding of the requirements for superconductivity, and more recently to other magnetic metal oxide systems where it has been shown to tune the magnetic properties of these materials. This review focuses on some important aspects of research on low temperature fluorine insertion reactions into pre-formed metal oxides, since 1998, and reports some new results. (C) 2006 Elsevier B.V. All rights reserved.

引用

页码：448 / 458

页数：11