A Compilation of Corrosion Potentials for Magnesium Alloys

被引：87

作者：

Cain, T. ^{[1
]}

Bland, L. G. ^{[1
]}

Birbilis, N. ^{[1
,2
]}

Scully, J. R. ^{[1
]}

机构：

[1] Univ Virginia, Dept Mat Sci & Engn, Charlottesville, VA 22904 USA

[2] Monash Univ, Dept Mat Engn, Clayton, Vic 3800, Australia

来源：

CORROSION | 2014年 / 70卷 / 10期

关键词：

chloride; corrosion potential; galvanic series; magnesium; metallic glass; BULK METALLIC-GLASS; ELECTROCHEMICAL PROPERTIES; LOCALIZED CORROSION; SUPERCOOLED LIQUID; BEHAVIOR; ND; MG65CU25Y10; CRYSTALLIZATION; RESISTANCE; TITANIUM;

D O I：

10.5006/1257

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A compilation of the reported corrosion potentials for Mg alloys and selected intermetallic compounds is presented. This study presents a galvanic series for Mg alloys based on a collection of data reported elsewhere, along with some experimental results. The paper classifies the relative potential bands that are realized as a result of alloying Mg. It is observed that the corrosion potential range of crystalline alloys, regardless of composition, remains rather narrow and in all cases <<1 V vs. the standard hydrogen electrode (SHE). Alloys containing Ca and commercial alloys containing large rare earth (RE) alloying content possess the most negative corrosion potentials while the aluminum zinc (AZ) series of alloys, along with magnesium-based metallic glasses, possess the most noble corrosion potentials. The work described is intended as a holistic summary and a guide in the context of galvanic relationships, in addition to providing a better insight in to the electrochemical character of commercial and experimental Mg alloys when viewed overall.

引用

页码：1043 / 1051

页数：9

共 55 条

[1] Corrosion behaviour of magnesium alloys coated with TiN by cathodic arc deposition in NaCl and Na2SO4solutions [J].

Altun, Hikmet ;

Sinici, Hakan .

MATERIALS CHARACTERIZATION, 2008, 59 (03) :266-270

[2]

[Anonymous], 2006, LIGHT ALLOYS TRADITI

[3] Corrosion processes of Mg-Y-Nd-Zr alloys in Na2SO4 electrolyte [J].

Ardelean, H. ;

Seyeux, A. ;

Zanna, S. ;

Prima, F. ;

Frateur, I. ;

Marcus, P. .

CORROSION SCIENCE, 2013, 73 :196-207

[4] Tracking the corrosion of magnesium sand cast AM50 alloy in chloride environments [J].

Asmussen, R. Matthew ;

Jakupi, Pellumb ;

Danaie, Mohsen ;

Botton, Gianluigi A. ;

Shoesmith, David W. .

CORROSION SCIENCE, 2013, 75 :114-122

[5] On the corrosion of binary magnesium-rare earth alloys [J].

Birbilis, N. ;

Easton, M. A. ;

Sudholz, A. D. ;

Zhu, S. M. ;

Gibson, M. A. .

CORROSION SCIENCE, 2009, 51 (03) :683-689

[6] Economical and environmental factors in light alloys automotive applications [J].

Caceres, Carlos H. .

METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2007, 38A (07) :1649-1662

[7] Potentiodynamic polarisation study of bulk metallic glasses based on the Mg-Zn-Ca ternary system [J].

Cao, J. D. ;

Laws, K. J. ;

Birbilis, N. ;

Ferry, M. .

CORROSION ENGINEERING SCIENCE AND TECHNOLOGY, 2012, 47 (05) :329-334

[8]

Cao J.D., 2013, BONE JOINT J B S15, V95, P32

[9] Technical Note: Experimental Survey of Corrosion Potentials for Rare Earth Metals Ce, Er, Gd, La, and Nd as a Function of pH and Chloride Concentration [J].

Chen, X-B. ;

Cain, T. ;

Scully, J. R. ;

Birbilis, N. .

CORROSION, 2014, 70 (04) :323-328

[10] Susceptibility of rare-earth-magnesium alloys to micro-galvanic corrosion [J].

Coy, A. E. ;

Viejo, F. ;

Skeldon, P. ;

Thompson, G. E. .

CORROSION SCIENCE, 2010, 52 (12) :3896-3906

← 1 2 3 4 5 6 →