A novel nopinone-based colorimetric and ratiometric fluorescent probe for detection of bisulfite and its application in food and living cells

被引：56

作者：

Jiang, Qian ^{[1
]}

Wang, Zhonglong ^{[1
]}

Li, Mingxin ^{[1
]}

Song, Jie ^{[2
]}

Yang, Yiqin ^{[3
,4
]}

Xu, Xu ^{[1
,4
]}

Xu, Haijun ^{[1
,4
]}

Wang, Shifa ^{[1
,4
]}

机构：

[1] Nanjing Forestry Univ, Coll Chem Engn, Nanjing 210037, Jiangsu, Peoples R China

[2] Univ Michigan, Dept Chem & Biochem, Flint, MI 48502 USA

[3] Nanjing Forestry Univ, Coll Light Ind & Food, Nanjing 210037, Jiangsu, Peoples R China

[4] Nanjing Forestry Univ, Coinnovat Ctr Efficient Proc & Utilizat Forest Re, Nanjing 210037, Jiangsu, Peoples R China

来源：

DYES AND PIGMENTS | 2019年 / 171卷

基金：

中国国家自然科学基金;

关键词：

Colorimetric and ratiometric; Fluorescent probe; Bisulfifite; Food samples; Cell imaging; AGGREGATION-INDUCED EMISSION; TURN-ON PROBE; LUMINESCENT POLYMERIC NANOPARTICLES; SULFUR-DIOXIDE DERIVATIVES; GENERATED SO2 DERIVATIVES; SELECTIVE DETECTION; FACILE FABRICATION; OPTICAL-PROPERTIES; SULFITE;

D O I：

10.1016/j.dyepig.2019.107702

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A colorimetric and ratiometric fluorescent probe DTF for HSO3- was synthesized from natural and renewable nopinone. The fluorescent probe DTF can quantitatively detect HSO3- with high selectivity, sensitivity and fast response time (60 s). The detection process was accompanied with the visible color change from yellow to colorless and the fluorescent color change from green to blue. The fluorescence intensity ratio (F-430/F-520) was linear with the concentration of HSO(3)(- )in the range of 0-80 mu M, with a limit detection of 79.2 nM. The sensing mechanism was confirmed by H-1 NMR and HRMS spectra. Above all, the novel fluorescent probe DTF was successfully applied to determine the concentration of HSO3- in food samples and HeLa cells.

引用

页数：7

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