Multifeedstock Biodiesel Production from a Blend of Five Oils through Transesterification with Variation of Moles Ratio of Oil: Methanol

被引:11
作者
Wahyono, Yoyon [1 ,3 ]
Hadiyanto [1 ,2 ,3 ]
Budihardjo, Mochamad Arief [4 ]
Hariyono, Yogi [5 ]
Baihaqi, Rifqi Ahmad [5 ]
机构
[1] Diponegoro Univ, Sch Postgrad Studies, Doctoral Program Environm Sci, Jl Imam Bardjo SH, Semarang 50241, Central Java, Indonesia
[2] Diponegoro Univ, Fac Engn, Dept Chem Engn, Jl Prof Soedharto, Semarang 50275, Central Java, Indonesia
[3] Diponegoro Univ, Ctr Biomass & Renewable Energy C BIORE, Jl Prof Soedharto, Semarang 50275, Central Java, Indonesia
[4] Diponegoro Univ, Fac Engn, Dept Environm Engn, Jl Prof Soedharto, Semarang 50275, Central Java, Indonesia
[5] Diponegoro Univ, Fac Sci & Math, Dept Phys, Jl Prof Soedharto, Semarang 50275, Central Java, Indonesia
关键词
Biodiesel; Moles; Multifeedstock; Production; Transesterification; MULTI-FEEDSTOCK BIODIESEL; SEED OIL; OPTIMIZATION; CASTOR; ESTERIFICATION; ETHANOLYSIS; FATS;
D O I
10.14716/ijtech.v13i3.4804
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This study was conducted to produce biodiesel from a mixture of 5 different oils i.e, palm oil, used cooking oil, soybean oil, canola oil, and sunflower oil, through transesterification under mole ratio variations of oil: methanol. The oils were mixed at a total volume of 300 mL with the same amount of each oil used. The transesterification of blended oils was conducted at 60 degrees C for 1 h, and the mole ratios of oil: methanol were set to 1:3, 1:6, 1:9, 1:12, and 1:15. The results demonstrated that the mole ratios of 1:6 resulted in the highest yield of 92.99% with the conversion of 99.58% mass. The gas chromatography-mass spectrometry (GCMS) results showed that all mole variations had a methyl ester percentage of more than 98% area. The FTIR analysis revealed peaks that indicated the presence of a methyl ester functional group and its long-chain (-R) for all variations. The methyl ester content, Density, acid value, and total glycerol test parameters were in accordance with the quality standards of ASTM D 6751, EN 14214, and SNI 7182-2015. Therefore, multi-feedstock biodiesel suitable for industrial-scale applications was successfully produced in this study.
引用
收藏
页码:606 / 618
页数:13
相关论文
共 42 条
[21]   Multi-Feedstock Biodiesel Production from Esterification of Calophyllum inophyllum Oil, Castor Oil, Palm Oil, and Waste Cooking Oil [J].
Hadiyanto, H. ;
Aini, Apsari Puspita ;
Widayat, W. ;
Kusmiyati, K. ;
Budiman, Arief ;
Rosyadi, Achmad .
INTERNATIONAL JOURNAL OF RENEWABLE ENERGY DEVELOPMENT-IJRED, 2020, 9 (01) :119-123
[22]  
Hadiyanto H., 2018, MATEC WEB C, V156, P1
[23]   Technologies for production of biodiesel focusing on green catalytic techniques: A review [J].
Helwani, Z. ;
Othman, M. R. ;
Aziz, N. ;
Fernando, W. J. N. ;
Kim, J. .
FUEL PROCESSING TECHNOLOGY, 2009, 90 (12) :1502-1514
[24]  
Indonesian National Standard, 2013, IND NAT STAND INS FR, V1
[25]   Biodiesel production from mixtures of canola oil and used cooking oil [J].
Issariyakul, Titipong ;
Kulkarni, Mangesh G. ;
Meher, Lekha C. ;
Dalai, Ajay K. ;
Bakhshi, Narendra N. .
CHEMICAL ENGINEERING JOURNAL, 2008, 140 (1-3) :77-85
[26]   Biodiesel production from heterotrophic microalgal oil [J].
Miao, XL ;
Wu, QY .
BIORESOURCE TECHNOLOGY, 2006, 97 (06) :841-846
[27]   Process parameter optimization for biodiesel production from mixed feedstock using empirical model [J].
Miraculas, G. Antony ;
Bose, N. ;
Raj, R. Edwin .
SUSTAINABLE ENERGY TECHNOLOGIES AND ASSESSMENTS, 2018, 28 :54-59
[28]  
Musa Idris Atadashi, 2016, Egyptian Journal of Petroleum, V25, P21, DOI 10.1016/j.ejpe.2015.06.007
[29]  
Nurhayati Amri TA, 2020, J PHYS C SER, V1655, P1
[30]   Recovery of oil via acid-catalyzed transesterification [J].
Obibuzor, JU ;
Abigor, RD ;
Okiy, DA .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2003, 80 (01) :77-80