Multifaceted [36]octaphyrin(1.1.1.1.1.1.1.1): deprotonation-induced switching among nonaromatic, Mobius aromatic, and Huckel antiaromatic species

被引：40
作者：
Cha, Won-Young [1 ,2 ]
Soya, Takanori [3 ]
Tanaka, Takayuki [3 ]
Mori, Hirotaka [3 ]
Hong, Yongseok [1 ,2 ]
Lee, Sangsu [1 ,2 ]
Park, Kyu Hyung [1 ,2 ]
Osuka, Atsuhiro [3 ]
Kim, Dongho [1 ,2 ]
机构：
[1] Yonsei Univ, Spect Lab Funct Elect Syst, Seoul 120749, South Korea
[2] Yonsei Univ, Dept Chem, Seoul 120749, South Korea
[3] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 6068502, Japan
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 36期
关键词：
SUBSTITUTED EXPANDED PORPHYRINS; INDEPENDENT CHEMICAL-SHIFTS; GEOMETRIC CONTRIBUTIONS; SEPARATION; CHEMISTRY;
D O I：
10.1039/c6cc02051h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Deprotonation of nonaromatic octakis-(pentafluorophenyl)-substituted [36]octaphyrin(1.1.1.1.1.1.1.1) with tetrabutylammonium fluoride (TBAF) afforded monoanionic twisted Mobius aromatic species and dianinonic square Huckel antiaromatic species, depending upon the amount of TBAF.
引用
收藏
页码：6076 / 6078
页数：3
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